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Abstract Changes in the upwelling and degassing of carbon from the Southern Ocean form one of the leading hypotheses for the cause of glacial-interglacial changes in atmospheric carbon dioxide. We present a 25,000-year-long Southern Ocean radiocarbon record reconstructed from deep-sea corals, which shows radiocarbon-depleted waters during the glacial period and through the early deglaciation. This depletion and associated deep stratification disappeared by ~14.6 ka (thousand years ago), consistent with the transfer of carbon from the deep ocean to the surface ocean and atmosphere via a Southern Ocean ventilation event. Given this evidence for carbon exchange in the Southern Ocean, we show that existing deep-ocean radiocarbon records from the glacial period are sufficiently depleted to explain the ~190 per mil drop in atmospheric radiocarbon between ~17 and 14.5 ka.

How is global temperature regulated? An experimental representation - Simple experiments to help pupils understand how different parameters regulate temperature at the Earth's surface. Interaction at the Air-Water Interface, part 1 - A very simple experiment to demonstrate gas exchange and equilibration at the boundary layer between air and water. Pupils will also observe acidification of water due to CO2 introduced directly in the water. Interaction at the Air-Water Interface, part 2 - A second set of experiment to demonstrate gas exchange and equilibration at the boundary layer between air and water. Pupils observe a high atmospheric CO2 concentration will produce water acidification. Uptake of Carbon Dioxide from the Water by Plants - The following experiments will demonstrate the role of plants in mitigating the acidification caused when CO2 is dissolved in water. Carbon Dioxide Fertilization of Marine Microalgae (Dunalliela sp.) Cultures: Marine microalgae in different atmospheric CO2 concentration - An experiment designed to illustrate the impact of carbon Dioxide on microalgal growth in the aquatic environment. Introduction to the principles of climate modelling - Working with real data in spreadsheets to create a climate model, students discover the global carbon budget and make their own predictions for the next century. Global carbon budget between 1958 and 2007 - Working with real global carbon budget data, students produce graphs to find the best representation of the data to make predictions about human CO2 emissions for the next century. This activity is also a nice application of percentages. Estimation of natural carbon sinks - Working with real global carbon budget data, students estimate how much of the CO2 emitted into the atmosphere as a result of human activities is absorbed naturally each year. How does temperature affect the solubility of CO2 en the water? - The following experiments will explore effects of water temperature on sol

Learn about the chemistry and biology behind our world's changing oceans, how humans are affecting our oceans, and what we can do to change it. See how increased carbon dioxide levels are changing ocean chemistry, and link chemistry to biology by examining the impacts of ocean acidification on marine organisms.

Ocean Acification Simulation Ocean AcidificationI developed this Carbonate Simulation to enables students and teachers to visualize how changes in atmospheric temperature and carbon dioxide concentrations may affect levels of carbon dioxide levels and related chemistry of the oceans. The applet uses coral reefs as an example of organisms that may be particularly affected by these changes in water chemistry.

"Study assesses nations' vulnerabilities to reduced mollusk harvests from ocean acidification August 2, 2011 Changes in ocean chemistry due to increased carbon dioxide (CO2) emissions are expected to damage shellfish populations around the world, but some nations will feel the impacts much sooner and more intensely than others, according to a study by scientists at Woods Hole Oceanographic Institution (WHOI)."

1 The carbon dioxide system in seawater: equilibrium chemistry and measurements 1.1 Introduction 1.2 Basic chemistry of carbon dioxide in seawater 1.3 The definition and measurement of pH in seawater 1.4 Implications of other acid-base equilibria in seawater on seawater alkalinity 1.5 Choosing the appropriate measurement techniques 1.6 Conclusions and recommendations 2 Approaches and tools to manipulate the carbonate chemistry 3 Atmospheric CO2 targets for ocean acidification perturbation experiments 4 Designing ocean acidification experiments to maximise inference 5 Bioassays, batch culture and chemostat experimentation 6 Pelagic mesocosms 7 Laboratory experiments and benthic mesocosm studies 8 In situ perturbation experiments: natural venting sites, spatial/temporal gradients in ocean pH, manipulative in situ p(CO2) perturbations 9 Studies of acid-base status and regulation 9.1 Introduction 9.2 Fundamentals of acid-base regulation 9.3 Measurement of pH, total CO2 and non-bicarbonate buffer values 9.4 Compartmental measurements: towards a quantitative picture 9.5 Overall suggestions for improvements 10 Studies of metabolic rate and other characters across life stages 10.1 Introduction 10.2 Definition of a frame of reference: studying specific characters across life stages 10.3 Approaches and methodologies: metabolic studies 10.4 Study of early life stages 10.5 Techniques for oxygen analyses 10.6 Overall suggestions for improvements 10.7 Data reporting 10.8 Recommendations for standards and guidelines 11 Production and export of organic matter 12 Direct measurements of calcification rates in planktonic organisms 13 Measurements of calcification and dissolution of benthic organisms and communities 14 Modelling considerations 15 Safeguarding and sharing ocean acidification data 15.1 Introduction 15.2 Sharing ocean acidification data 15.3 Safeguarding ocean acidification data 15.4 Harmonising ocean acidification data and metadata 15.5 Disseminating ocean

"As the amount of Carbon Dioxide continues to build up in the atmosphere it is also changing the chemistry of the ocean. Ocean surveys and modeling studies have revealed that the pH of the ocean is decreasing (which means the ocean is becoming more acidic) due to increasing concentrations of carbon Dioxide. This changing oceanic environment will have severe implications for life in the ocean. COSEE NOW is pleased to present A plague in air and sea: Neutralizing the acid of progress a new audio slideshow that features Debora Inglesias-Rodriguez. In this scientist profile, Dr. Inglesias-Rodriguez, a Biological Oceanographer at the University of Southampton National Oceanography Centre, shares her story of how she grew up loving the ocean and became interested in science. She also explains how witnessing the effects of climate change has lead her to research how organisms like Sea Urchins are being affected by ocean acidification. Download A plague in air and sea: Neutralizing the acid of progress"

Ocean Probes To Help Refine Climate Change Forecasting; 'Oceanography Is Risky; You Lose Things' by Underwatertimes.com News Service - August 5, 2011 17:43 EST LOS ANGELES, California -- A USC researcher has opened a new window to understanding how the ocean impacts climate change. Lisa Collins, environmental studies lecturer with the USC Dornsife College, spent four years collecting samples from floating sediment traps in the San Pedro Basin off the Los Angeles coast, giving scientists a peek at how much carbon is locked up in the ocean and where it comes from. Collins' research suggests that the majority of particulate organic carbon (POC) falling to the basin floor is marine-derived, not the result of runoff from rainfall. This means that the ocean off the coast of Southern California is acting as a carbon "sink" - taking carbon out of the atmosphere via phytoplankton and locking it up in sediment. Though estimates regarding the effect of carbon in the ocean already exist, her hard data can help climatologists create more accurate predictions of how carbon will impact global warming. What is unique about Collins' study is that it is not just a snapshot of POC falling, but rather a finely detailed record of four years of POC production, showing how much fell and when. "It's all tied to climate change," said Collins, who started the research as a graduate student working for USC Earth Sciences Professor Will Berelson. "This lets us see patterns. "Our data can help climate modelers better predict the interactions between the oceans and atmosphere with respect to carbon which can help them better predict how much carbon dioxide will end up sequestered over the long term as sediments in the ocean," she said. Collins' study is among the longest of its kind in the region. A similar study was conducted in Santa Monica Basin from 1985-1991, and another is currently underway in Hawaii. Her findings appear in the August issue of Deep-Sea Research I. Between Janua

"USC researcher experiments with changing ocean chemistry Jan. 19, 2011 | Molly Peterson | KPCC In his lab, USC's Dave Hutchins is simulating possible future atmospheres and temperatures for the Earth. He says he's trying to figure out how tiny organisms that form the base of the food web will react to a more carbon-intense ocean. Burning fossil fuels doesn't just put more carbon into the atmosphere and help warm the climate. It's also changing the chemistry of sea water. KPCC's Molly Peterson visits a University of Southern California researcher who studies the consequences of a more corrosive ocean. Tailpipes and refineries and smokestacks as far as the eye can see in Los Angeles symbolize the way people change the planet's climate. They remind Dave Hutchins that the ocean's changing too. Hutchins teaches marine biology at USC. He says about a third of all the carbon, or CO2, that people have pushed into earth's atmosphere ends up in sea water - "which is a good thing for us because if the ocean hadn't taken up that CO2 the greenhouse effect would be far more advanced than it is." He smiles. Hutchins says that carbon is probably not so good for the ocean. "The more carbon dioxide that enters the ocean the more acidic the ocean gets." On the pH scale, smaller numbers represent more acidity. The Monterey Bay Aquarium Research Institute estimates we've pumped 500 million tons of carbon into the world's oceans. Dave Hutchins at USC says that carbon has already lowered the pH value for sea water. "By the end of this century we are going to have increased the amount of acid in the ocean by maybe 200 percent over natural pre-industrial levels," he says. "So we are driving the chemistry of the ocean into new territory - into areas that it has never seen." Hutchins is one of dozens of scientists who study the ripples of that new chemistry into the marine ecosystem. Now for an aside. I make bubbly water at home with a soda machine, and to do that, I pump ca

Science On a Sphere Well-crafted visualizations provide unique and powerful teaching tools Science On a Sphere® is a large visualization system that uses computers and video projectors to display animated data onto the outside of a sphere. Researchers at NOAA developed Science On a Sphere® as an educational tool to help illustrate Earth System science to people of all ages. Animated images of complex processes such as ocean currents, sea level rise, and ocean acidification are used to to enhance the public's understanding of our dynamic environment. Ocean Acidification on Science On a Sphere® The movies below were developed for use on Science On a Sphere® and show computer model simulations of surface ocean pH and carbonate mineral saturation state for the years 1895 to 2094. The first movie shows a computer recreation of surface ocean pH from 1895 to the present, and it forecasts how ocean pH will drop even more between now and 2094. Dark gray dots show cold-water coral reefs. Medium gray dots show warm-water coral reefs. You can see that ocean acidification was slow at the beginning of the movie, but it speeds up as time goes on. This is because humans are releasing carbon dioxide faster than the atmosphere-ocean system can handle.

"The Orangeburg Scarp, a band of hard, crusty sediment teeming with tiny plankton fossils that runs from Florida to Virginia, marks an ancient shoreline where waves eroded bedrock 3 million years ago. That period, the middle Pliocene, saw carbon dioxide levels and temperatures that many scientists say could recur by 2100. The question is: Could those conditions also result in Pliocene-epoch sea levels within the next 10 to 20 centuries, sea levels that may have been as much as 35 meters higher than they are today? The answer, say climate scientists, may lie 17,000 kilometers away in East Antarctica. The East Antarctic Ice Sheet is the world's largest, a formation up to 4 km thick and 11 million km2 in area that covers three-quarters of the southernmost continent. Its glaciers were thought to sit mostly above sea level, protecting them from the type of ocean-induced losses that are affecting the West Antarctic Ice Sheet. But studies of ancient sea levels that focus on the Orangeburg Scarp and other sites challenge that long-held assumption. Not everybody believes the records from Orangeburg. But combined with several other new lines of evidence, they support the idea that parts of East Antarctica could indeed be more prone to melting than expected. "