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"Recognising ocean acidification in deep time: An evaluation of the evidence for acidification across the Triassic-Jurassic boundary Sarah E. GreeneCorresponding author contact information, 1, E-mail the corresponding author, Rowan C. Martindale1, E-mail the corresponding author, Kathleen A. Ritterbush E-mail the corresponding author, David J. Bottjer E-mail the corresponding author, Frank A. Corsetti E-mail the corresponding author, William M. Berelson E-mail the corresponding author Department of Earth Sciences, University of Southern California, Los Angeles, California, USA 90089 Received 22 July 2011. Accepted 17 March 2012. Available online 5 April 2012. While demonstrating ocean acidification in the modern is relatively straightforward (measure increase in atmospheric CO2 and corresponding ocean chemistry change), identifying palaeo-ocean acidification is problematic. The crux of this problem is that the rock record is a constructive archive while ocean acidification is essentially a destructive (and/or inhibitory) phenomenon. This is exacerbated in deep time without the benefit of a deep ocean record. Here, we discuss the feasibility of, and potential criteria for, identifying an acidification event in deep time. Furthermore, we investigate the evidence for ocean acidification during the Triassic-Jurassic (T-J) boundary interval, an excellent test case because 1) it occurs in deep time, beyond the reach of deep sea drilling coverage; 2) a potential trigger for acidification is known; and 3) it is associated with one of the 'Big Five' mass extinctions which disproportionately affected modern-style invertebrates. Three main criteria suggest that acidification may have occurred across the T-J transition. 1) The eruption of the Central Atlantic Magmatic Province (CAMP) and the associated massive and rapid release of CO2 coincident with the end-Triassic mass extinction provide a suitable trigger for an acidification event (

1 The carbon dioxide system in seawater: equilibrium chemistry and measurements 1.1 Introduction 1.2 Basic chemistry of carbon dioxide in seawater 1.3 The definition and measurement of pH in seawater 1.4 Implications of other acid-base equilibria in seawater on seawater alkalinity 1.5 Choosing the appropriate measurement techniques 1.6 Conclusions and recommendations 2 Approaches and tools to manipulate the carbonate chemistry 3 Atmospheric CO2 targets for ocean acidification perturbation experiments 4 Designing ocean acidification experiments to maximise inference 5 Bioassays, batch culture and chemostat experimentation 6 Pelagic mesocosms 7 Laboratory experiments and benthic mesocosm studies 8 In situ perturbation experiments: natural venting sites, spatial/temporal gradients in ocean pH, manipulative in situ p(CO2) perturbations 9 Studies of acid-base status and regulation 9.1 Introduction 9.2 Fundamentals of acid-base regulation 9.3 Measurement of pH, total CO2 and non-bicarbonate buffer values 9.4 Compartmental measurements: towards a quantitative picture 9.5 Overall suggestions for improvements 10 Studies of metabolic rate and other characters across life stages 10.1 Introduction 10.2 Definition of a frame of reference: studying specific characters across life stages 10.3 Approaches and methodologies: metabolic studies 10.4 Study of early life stages 10.5 Techniques for oxygen analyses 10.6 Overall suggestions for improvements 10.7 Data reporting 10.8 Recommendations for standards and guidelines 11 Production and export of organic matter 12 Direct measurements of calcification rates in planktonic organisms 13 Measurements of calcification and dissolution of benthic organisms and communities 14 Modelling considerations 15 Safeguarding and sharing ocean acidification data 15.1 Introduction 15.2 Sharing ocean acidification data 15.3 Safeguarding ocean acidification data 15.4 Harmonising ocean acidification data and metadata 15.5 Disseminating ocean

"USC researcher experiments with changing ocean chemistry Jan. 19, 2011 | Molly Peterson | KPCC In his lab, USC's Dave Hutchins is simulating possible future atmospheres and temperatures for the Earth. He says he's trying to figure out how tiny organisms that form the base of the food web will react to a more carbon-intense ocean. Burning fossil fuels doesn't just put more carbon into the atmosphere and help warm the climate. It's also changing the chemistry of sea water. KPCC's Molly Peterson visits a University of Southern California researcher who studies the consequences of a more corrosive ocean. Tailpipes and refineries and smokestacks as far as the eye can see in Los Angeles symbolize the way people change the planet's climate. They remind Dave Hutchins that the ocean's changing too. Hutchins teaches marine biology at USC. He says about a third of all the carbon, or CO2, that people have pushed into earth's atmosphere ends up in sea water - "which is a good thing for us because if the ocean hadn't taken up that CO2 the greenhouse effect would be far more advanced than it is." He smiles. Hutchins says that carbon is probably not so good for the ocean. "The more carbon dioxide that enters the ocean the more acidic the ocean gets." On the pH scale, smaller numbers represent more acidity. The Monterey Bay Aquarium Research Institute estimates we've pumped 500 million tons of carbon into the world's oceans. Dave Hutchins at USC says that carbon has already lowered the pH value for sea water. "By the end of this century we are going to have increased the amount of acid in the ocean by maybe 200 percent over natural pre-industrial levels," he says. "So we are driving the chemistry of the ocean into new territory - into areas that it has never seen." Hutchins is one of dozens of scientists who study the ripples of that new chemistry into the marine ecosystem. Now for an aside. I make bubbly water at home with a soda machine, and to do that, I pump ca

The term ocean acidification is used to describe the ongoing decrease in ocean pH caused by human CO2 emissions, such as the burning of fossil fuels. It is the little known consequence of living in a high CO2 world, dubbed at the 2009 United Nations Climate Change Conference (COP15) as the "evil twin of climate change". The oceans currently absorb approximately half of the CO2 produced by burning fossil fuel; put simply, climate change would be far worse if it were not for the oceans. However, there is a cost to the oceans - when CO2 dissolves in seawater it forms carbonic acid and as more CO2 is taken up by the oceans surface, the pH decreases, moving towards a less alkaline and therefore more acidic state. Already ocean pH has decreased by about 30% and if we continue emitting CO2 at the same rate by 2100 ocean acidity will increase by about 150%, a rate that has not been experienced for at least 400,000 years. Such a monumental alteration in basic ocean chemistry is likely to have wide implications for ocean life, especially for those organisms that require calcium carbonate to build shells or skeletons. Ocean acidification is a relatively new field of research, with most of the studies having been conducted over the last decade. While it is gaining some attention among policy makers, international leaders and the media, scientists find there is still a lack of understanding.

Science On a Sphere Well-crafted visualizations provide unique and powerful teaching tools Science On a Sphere® is a large visualization system that uses computers and video projectors to display animated data onto the outside of a sphere. Researchers at NOAA developed Science On a Sphere® as an educational tool to help illustrate Earth System science to people of all ages. Animated images of complex processes such as ocean currents, sea level rise, and ocean acidification are used to to enhance the public's understanding of our dynamic environment. Ocean Acidification on Science On a Sphere® The movies below were developed for use on Science On a Sphere® and show computer model simulations of surface ocean pH and carbonate mineral saturation state for the years 1895 to 2094. The first movie shows a computer recreation of surface ocean pH from 1895 to the present, and it forecasts how ocean pH will drop even more between now and 2094. Dark gray dots show cold-water coral reefs. Medium gray dots show warm-water coral reefs. You can see that ocean acidification was slow at the beginning of the movie, but it speeds up as time goes on. This is because humans are releasing carbon dioxide faster than the atmosphere-ocean system can handle.

"What are the impacts of ocean acidification on key benthic (seabed) ecosystems, communities, habitats, species and their life cycles? The average acidity (pH) of the world's oceans has been stable for the last 25 million years. However, the oceans are now absorbing so much man made CO2 from the atmosphere that measurable changes in seawater pH and carbonate chemistry can be seen. It is predicted that this could affect the basic biological functions of many marine organisms. This in turn could have implications for the survival of populations and communities, as well as the maintenance of biodiversity and ecosystem function. In the seas around the UK, the habitats that make up the seafloor, along with the animals associated with them, play a crucial role in maintaining a healthy and productive marine ecosystem. This is important considering 40% of the world's population lives within 100km of the coast and many of these people depend on coastal systems for food, economic prosperity and well-being. Given that coastal habitats also harbour incredibly high levels of biodiversity, any environmental change that affects these important ecosystems could have substantial environmental and economical impacts. During several recent international meetings scientific experts have concluded that new research is urgently needed. In particular we need long-term studies that determine: which organisms are likely to be tolerant to high CO2 and which are vulnerable; whether organisms will have time to adapt or acclimatise to this rapid environmental change; and how the interactions between individuals that determine ecosystem structure will be affected. This current lack of understanding is a major problem as ocean acidification is a rapidly evolving management issue and, with an insufficient knowledge base, policy makers and managers are struggling to formulate effective strategies to sustain and protect the marine environment in the face of ocean acidification."

Global warming…the Earth is steadily getting warmer. The why is it getting warmer question will solicit so many theories that it would drive one mad to sort through them all. Global warming itself is sort of a misnomer; it is a symptom of the problem, not the cause. The cause for all the debate is whether or not the atmospheric increase of CO2 gas over the last two-hundred years has affected the Earth's climate. Recently scientists have discovered another reason to be concerned about the increasing level of atmospheric CO2. It is startling that the media and science has hardly touched upon ocean acidification. It would not be surprising if you have never heard this term. A LexisNexis search of the news wire services found in the past week there were 348 articles that mentioned global warming. Three articles contained ocean acidification. In the last 2 years, a LexisNexis search of all sources found a mere 216 articles that mentioned ocean acidification. That is a worldwide search of newspapers, magazines and wire services. The New York Times did not mention it a single time, but they ran so many Global Warming articles that there were too many matches for the page to display.

"As the amount of Carbon Dioxide continues to build up in the atmosphere it is also changing the chemistry of the ocean. Ocean surveys and modeling studies have revealed that the pH of the ocean is decreasing (which means the ocean is becoming more acidic) due to increasing concentrations of carbon dioxide. This changing oceanic environment will have severe implications for life in the ocean. COSEE NOW is pleased to present A plague in air and sea: Neutralizing the acid of progress a new audio slideshow that features Debora Inglesias-Rodriguez. In this scientist profile, Dr. Inglesias-Rodriguez, a Biological Oceanographer at the University of Southampton National Oceanography Centre, shares her story of how she grew up loving the ocean and became interested in science. She also explains how witnessing the effects of climate change has lead her to research how organisms like Sea Urchins are being affected by ocean acidification. Download A plague in air and sea: Neutralizing the acid of progress"

Covering Ocean Acidification: Chemistry and Considerations Marah Hardt and Carl Safina June 24, 2008 Changing ocean chemistry threatens the survival of marine life as much as warming temperatures. Understanding the basic chemistry of ocean acidification and the relevant consequences for people and wildlife are keys to effective journalism on an issue of growing importance and interest to media audiences.

"As the amount of Carbon Dioxide continues to build up in the atmosphere it is also changing the chemistry of the ocean. Ocean surveys and modeling studies have revealed that the pH of the ocean is decreasing (which means the ocean is becoming more acidic) due to increasing concentrations of carbon dioxide. This changing oceanic environment will have severe implications for life in the ocean. COSEE NOW is pleased to present A plague in air and sea: Neutralizing the acid of progress a new audio slideshow that features Debora Inglesias-Rodriguez. In this scientist profile, Dr. Inglesias-Rodriguez, a Biological Oceanographer at the University of Southampton National Oceanography Centre, shares her story of how she grew up loving the ocean and became interested in science. She also explains how witnessing the effects of climate change has lead her to research how organisms like Sea Urchins are being affected by ocean acidification."

The Inter-Academy Panel on International Issues (or IAP) has today launched a statement signed by 100 of the world's leading science academies calling for ocean acidification to be placed on the agenda for the UNFCCC talks being held in Bonn over the next two weeks.

"Study assesses nations' vulnerabilities to reduced mollusk harvests from ocean acidification August 2, 2011 Changes in ocean chemistry due to increased carbon dioxide (CO2) emissions are expected to damage shellfish populations around the world, but some nations will feel the impacts much sooner and more intensely than others, according to a study by scientists at Woods Hole Oceanographic Institution (WHOI)."

Learn about the chemistry and biology behind our world's changing oceans, how humans are affecting our oceans, and what we can do to change it. See how increased carbon dioxide levels are changing ocean chemistry, and link chemistry to biology by examining the impacts of ocean acidification on marine organisms.