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1 The carbon dioxide system in seawater: equilibrium chemistry and measurements 1.1 Introduction 1.2 Basic chemistry of carbon dioxide in seawater 1.3 The definition and measurement of pH in seawater 1.4 Implications of other acid-base equilibria in seawater on seawater alkalinity 1.5 Choosing the appropriate measurement techniques 1.6 Conclusions and recommendations 2 Approaches and tools to manipulate the carbonate chemistry 3 Atmospheric CO2 targets for ocean acidification perturbation experiments 4 Designing ocean acidification experiments to maximise inference 5 Bioassays, batch culture and chemostat experimentation 6 Pelagic mesocosms 7 Laboratory experiments and benthic mesocosm studies 8 In situ perturbation experiments: natural venting sites, spatial/temporal gradients in ocean pH, manipulative in situ p(CO2) perturbations 9 Studies of acid-base status and regulation 9.1 Introduction 9.2 Fundamentals of acid-base regulation 9.3 Measurement of pH, total CO2 and non-bicarbonate buffer values 9.4 Compartmental measurements: towards a quantitative picture 9.5 Overall suggestions for improvements 10 Studies of metabolic rate and other characters across life stages 10.1 Introduction 10.2 Definition of a frame of reference: studying specific characters across life stages 10.3 Approaches and methodologies: metabolic studies 10.4 Study of early life stages 10.5 Techniques for oxygen analyses 10.6 Overall suggestions for improvements 10.7 Data reporting 10.8 Recommendations for standards and guidelines 11 Production and export of organic matter 12 Direct measurements of calcification rates in planktonic organisms 13 Measurements of calcification and dissolution of benthic organisms and communities 14 Modelling considerations 15 Safeguarding and sharing ocean acidification data 15.1 Introduction 15.2 Sharing ocean acidification data 15.3 Safeguarding ocean acidification data 15.4 Harmonising ocean acidification data and metadata 15.5 Disseminating ocean

Winds of Change Jane Qiu Antarctica does not respond to global warming uniformly like a giant ice cube. Changing wind patterns are an unsung force shaping Antarctica's future. Retreating sea ice and stronger winds have caused seawater to mix more deeply, a process that churns sunlight-dependent phytoplankton into the ocean's depths. As a result, phytoplankton biomass has declined by 12% over the past 30 years. Higher on the food chain, that means fewer krill and fish larvae. These creatures are also getting hammered by the loss of sea ice, which hides them from predators. The complex interplay between air, sea, and ice has emerged as a central theme underlying climate change in Antarctica. Shifting wind patterns and corresponding ocean changes can explain climate responses across the continent.

NARRATOR: Even though the ocean covers seventy percent of the Earth's surface, people tend to know more information about land than the sea. As a result, our understanding of the ocean is often incomplete or full of misconceptions. How well do you know the ocean? You may think Earth has five separate oceans. They're clearly labeled on our maps. But, in actuality, these are all connected, and part of one global ocean system. Ever wonder why the ocean is blue? You may have heard its because the water reflects the color of the sky. Not quite. Sunlight contains all the colors of the rainbow. When it hits the ocean, it gets scattered by the water molecules. Blue light is scattered the most, which is why the ocean appears blue. Even more interesting is that floating plants and sediments in the water can cause light to bounce in such a way for the ocean to appear green, yellow, and even red! Another idea some people have is that the sea floor is flat. Actually, just like land, the sea floor has canyons, plains, and mountain ranges. And many of these features are even bigger than those found on land. You may also think that our ocean's saltwater is just a mix of water and table salt. Not so. Seawater's "salt" is actually made of dissolved minerals from surface runoff. That is, excess water from rain and melting snow flowing over land and into the sea. This is why the ocean doesn't have the same level of salinity everywhere. Salinity varies by location and season. Finally, you may have heard that melting sea ice will cause sea levels to rise. In reality, sea ice is just frozen seawater, and because it routinely freezes and melts, its volume is already accounted for in the ocean. Sea levels can rise, however, from ice that melts off land and into the ocean. Understanding basic facts about the ocean is important since it affects everything from our atmosphere to our ecosystems. By knowing your ocean, you are better prepared to help protect it.

"Abstract The Phanerozoic fossil record of marine animal diversity covaries with the amount of marine sedimentary rock. The extent to which this covariation reflects a geologically controlled sampling bias remains unknown. We show that Phanerozoic records of seawater chemistry and continental flooding contain information on the diversity of marine animals that is independent of sedimentary rock quantity and sampling. Interrelationships among variables suggest long-term interactions among continental flooding, sulfur and carbon cycling, and macroevolution. Thus, mutual responses to interacting Earth systems, not sampling biases, explain much of the observed covariation between Phanerozoic patterns of sedimentation and fossil biodiversity. Linkages between biodiversity and environmental records likely reflect complex biotic responses to changing ocean redox conditions and long-term sea-level fluctuations driven by plate tectonics. "

"What are the impacts of ocean acidification on key benthic (seabed) ecosystems, communities, habitats, species and their life cycles? The average acidity (pH) of the world's oceans has been stable for the last 25 million years. However, the oceans are now absorbing so much man made CO2 from the atmosphere that measurable changes in seawater pH and carbonate chemistry can be seen. It is predicted that this could affect the basic biological functions of many marine organisms. This in turn could have implications for the survival of populations and communities, as well as the maintenance of biodiversity and ecosystem function. In the seas around the UK, the habitats that make up the seafloor, along with the animals associated with them, play a crucial role in maintaining a healthy and productive marine ecosystem. This is important considering 40% of the world's population lives within 100km of the coast and many of these people depend on coastal systems for food, economic prosperity and well-being. Given that coastal habitats also harbour incredibly high levels of biodiversity, any environmental change that affects these important ecosystems could have substantial environmental and economical impacts. During several recent international meetings scientific experts have concluded that new research is urgently needed. In particular we need long-term studies that determine: which organisms are likely to be tolerant to high CO2 and which are vulnerable; whether organisms will have time to adapt or acclimatise to this rapid environmental change; and how the interactions between individuals that determine ecosystem structure will be affected. This current lack of understanding is a major problem as ocean acidification is a rapidly evolving management issue and, with an insufficient knowledge base, policy makers and managers are struggling to formulate effective strategies to sustain and protect the marine environment in the face of ocean acidification."

The term ocean acidification is used to describe the ongoing decrease in ocean pH caused by human CO2 emissions, such as the burning of fossil fuels. It is the little known consequence of living in a high CO2 world, dubbed at the 2009 United Nations Climate Change Conference (COP15) as the "evil twin of climate change". The oceans currently absorb approximately half of the CO2 produced by burning fossil fuel; put simply, climate change would be far worse if it were not for the oceans. However, there is a cost to the oceans - when CO2 dissolves in seawater it forms carbonic acid and as more CO2 is taken up by the oceans surface, the pH decreases, moving towards a less alkaline and therefore more acidic state. Already ocean pH has decreased by about 30% and if we continue emitting CO2 at the same rate by 2100 ocean acidity will increase by about 150%, a rate that has not been experienced for at least 400,000 years. Such a monumental alteration in basic ocean chemistry is likely to have wide implications for ocean life, especially for those organisms that require calcium carbonate to build shells or skeletons. Ocean acidification is a relatively new field of research, with most of the studies having been conducted over the last decade. While it is gaining some attention among policy makers, international leaders and the media, scientists find there is still a lack of understanding.

"Study assesses nations' vulnerabilities to reduced mollusk harvests from ocean acidification August 2, 2011 Changes in ocean chemistry due to increased carbon dioxide (CO2) emissions are expected to damage shellfish populations around the world, but some nations will feel the impacts much sooner and more intensely than others, according to a study by scientists at Woods Hole Oceanographic Institution (WHOI)."