Group items tagged

Molybdenum and tungsten are redox-sensitive elements, and their stable isotope ratios have attracted attention as paleoceanographic proxies. However, our knowledge of the distribution of stable Mo and W isotopes in the modern hydrosphere remains limited. In this study, we provided the concentrations and isotope ratios of dissolved Mo and W in the oceans (the North Pacific and Indian Oceans), marginal seas (the East China Sea and Sea of Japan), and a river-estuary system in Japan (from the Uji-Yodo rivers to Osaka Bay). In the North Pacific and Indian Oceans, the W concentration was 48.2 ± 6.2 pmol/kg (ave ± 2sd, n = 109), δ186/184W was 0.52 ± 0.06 ‰, the Mo concentration was 105.1 ± 8.0 nmol/kg, and δ98/95Mo was 2.40 ± 0.06 ‰. The results indicate that W has the constant concentration and isotopic composition in the modern ocean as well as Mo. In the East China Sea and the Sea of Japan, the W concentration and δ186/184W in the upper water (< 1000 m depth) were different from those in the ocean (W = 56 ± 18 pmol/kg, δ186/184W = 0.45 ± 0.06 ‰, n = 24). However, the concentrations in deeper water were congruent with those in the oceans (W = 49.9 ± 7.6 pmol/kg, δ186/184W = 0.50 ± 0.02 ‰, n = 7). The Mo concentration was 105.4 ± 3.1 nmol/kg and δ98/95Mo was 2.36 ± 0.03 ‰ (n = 31) throughout the water column, congruent with those in the ocean. In the Uji River-Yodo River-Osaka Bay system, the W concentration reached 1074 pmol/kg and δ186/184W reached 0.20 ‰. We propose that the enrichment of W with a low δ186/184W in the river-estuary system and marginal seas is caused by anthropogenic pollution. Anthropogenic Mo pollution was not detected in marginal seas. However, the Mo concentration and δ98/95Mo showed high anomalies above the mixing line of river water and seawater in the lower Yodo River and Osaka Bay, implying possible anthropogenic pollution of Mo in the metropolitan area.

Stable isotope analysis of dermis was used to examine foraging behavior of whale sharks at Ningaloo Reef in Western Australia. Values of δ13C and δ15N in dermis were compared to those obtained from likely species of local prey. The δ13C values of zooplankton and nektonic taxa at Ningaloo ranged from −18.9‰ to −16.5‰ reflecting the different carbon sources (from pelagic to more inshore and benthic) entering the food web. Isotopic values also varied depending on the diet-to-tissue discrimination factor applied in the analysis. When data was corrected using factors derived from slow turnover, structural cartilage in fins, whale sharks showed a greater reliance on pelagic food webs, whereas analyses using raw data suggested a greater dietary component from benthic and inshore habitats. Variability in δ15N values (6.9‰ to 10.8‰) implied different patterns of foraging among whale sharks, likely indicating movement among foraging localities that occur at Ningaloo Reef and along the Western Australian coast. There was evidence of enrichment in 15N occurring with increasing size in males and females, a pattern that could have been due to changes in growth rate and trophic level with age and/or an ontogenetic shift in feeding grounds. Given the variability potentially induced in stable isotope values by differences in rates of turnover of tissues and the use of diet-to-tissue discrimination factors, future studies would benefit from a multi-technique approach using different tissues to identify the diet of whale sharks.

The Ninety-east Ridge (NER) is located in the southern Bay of Bengal in the northeast Indian Ocean and is composed of pelagic and hemipelagic sediments. In addition to contributions from marine biomass, the ridge also contains terrestrially sourced sedimentary material. However, considerable disagreement remains regarding the origin of these terrestrial materials and transport pathways. This paper discusses the collection of seafloor surface sediments and three sediment cores recovered from the northern region of the NER, as well as the analysis of clay minerals, Sr-Nd isotopes, and sediment grain size. The ages of the three core sediments are constrained by AMS 14C dating to better establish the source and transport pathways of the terrestrial materials within NER sediments over the past 35000 years. The research results show that the Qinghai-Tibet Plateau is the predominate source of terrigenous sedimentary material in the NER. In the plateau, the crustal materials were weathered and stripped and then transported to the Andaman Sea via the Irrawaddy River. From there, the material was transported westward by monsoon-driven circulation to the northernmost part of the NER before being transported to the south for final deposition. This transport mode has changed little over the past 35000 years. However, during the rapidly changing climate of the Younger Dryas (12.9~11.5 ka BP), there were some variations in the input amount, grain size, and Sr-Nd isotope value of the source material. The above conclusions are significant for re-evaluating the source of terrigenous sediments, the temporal and spatial changes in transport modes, and the sensitivity of the NER to climatic shifts.

The recently discovered Onnuri hydrothermal vent field (OVF) is a typical off-axis ultramafic-hosted vent system, located on the summit of the dome-like ocean core complex (OCC) at a distance of ∼12 km from the ridge axis along the middle region of the Central Indian Ridge (CIR). The plume chemistry with high methane anomaly was consistent with the precursor of hydrothermal activity; however, the fundamental characteristic of the OVF system, such as the hydrothermal circulation process and source of heat, remains poorly understood. Here, we focus on the geochemical features of surface sediments and minerals collected at and around the OVF region in order to better understand this venting system. The results reveal that the OVF sediments are typified by remarkably high concentrations of Fe, Si, Ba, Cu, and Zn, derived from hydrothermal fluid and S and Mg from seawater; depleted C-S isotope compositions; and abundant hydrothermally precipitated minerals (i.e., Fe-Mn hydroxides, sulfide and sulfate minerals, and opal silica). Notably, the occurrence of pure talc and barite bears witness to strong hydrothermal activity in the OVF, and their sulfur and strontium isotope geochemistry agree with extensive mixing of the unmodified seawater with high-temperature fluid derived from the gabbroic rock within the ultramafic-dominated ridge segment. The findings reveal that the OVF is a representative example of an off-axis, high-temperature hydrothermal circulation system, possibly driven by the exothermic serpentinization of exposed peridotites. Given the widespread distribution of OCC with detachment faults, furthermore, the OVF may be the most common type of hydrothermal activity in the CIR, although the paucity of data precludes generalizing this result. This study provides important information contributing to our understanding of the ultramafic-hosted hydrothermal vent system with a non-magmatic heat source along mid-ocean ridges.

The western Indian continental shelf houses the world's largest naturally formed coastal low-oxygen zone that develops seasonally during the summer monsoon. We investigated multiple reductive nitrogen transformation pathways and quantified their rates in this system through anaerobic incubations with additions of 15N-labeled substrates during the anoxic period for three consecutive years (2008-2010). Addition of 15N labeled ammonium (15NH4+) resulted in low to moderate anaerobic ammonia oxidation (Anammox) rates in about half of our incubations from the oxygen depleted waters. In contrast, incubations with labeled nitrite (15NO2-) led to large production of 30N2 over 29N2 in all incubation experiments, indicating denitrification to be the dominant N-loss pathway. Rates of dissimilatory nitrate/nitrite reduction to ammonium (DNRA) were found to be highly variable and were lower by an order of magnitude than the denitrification rates. Extrapolation of average rates over the sampling periods and volume of anoxic waters showed large nitrogen removal (3.70-11.1 Tg year-1) which is about three times as high as the previously reported estimate (1.3-3.8 Tg year-1). Despite the small area it occupies, this shallow seasonal anoxic zone may account for as much as 20-60% the of the total annual fixed nitrogen loss in the perennial oxygen minimum zone of the Arabian Sea.

In this study, we presented a high-resolution benthic foraminiferal assemblage record from the western Bay of Bengal (BoB) (off Krishna-Godavari Basin) showing millennial-scale variations during the last 45 ka. We studied temporal variations in benthic foraminiferal assemblages (relative abundances of ecologically sensitive groups/species, microhabitat categories, and morphogroups) to infer past changes in sea bottom environment and to understand how monsoon induced primary productivity-driven organic matter export flux and externally sourced deep-water masses impacted the deep-sea environment at the core site. Our records reveal a strong coupling between surface productivity and benthic environment on glacial/interglacial and millennial scale in concert with Northern Hemisphere climate events. Faunal data suggest a relatively oxic environment when the organic matter flux to the sea floor was low due to low primary production during intensified summer monsoon attributing surface water stratification and less nutrient availability in the mixed layer. Furthermore, records of oxygen-sensitive benthic taxa (low-oxygen vs. high-oxygen benthics) indicate that changes in deep-water circulation combined with the primary productivity-driven organic matter flux modulated the sea bottom oxygen condition over the last 45 ka. We suggest that the bottom water at the core site was well-ventilated during the Holocene (except for the period since 3 ka) compared with the late glacial period. At the millennial timescale, our faunal proxy records suggest relatively oxygen-poor condition at the sea floor during the intervals corresponding to the cold stadials and North Atlantic Heinrich events (H1, H2, H3, and H4) compared with the Dansgaard/Oeschger (D-O) warm interstadials. The study further reveals oxygen-poor bottom waters during the last glacial maximum (LGM, 19-22 ka) which is more pronounced during 21-22 ka. A major shift in sea bottom condition from an oxygenated bottom wa

Researchers led by Prof. WAN Shiming from the Institute of Oceanology of the Chinese Academy of Sciences (IOCAS) and their collaborators reported a continuous weathering record spanning the past 37 million years, which was based on planktonic foraminiferal neodymium isotopes (εNd) of marine sediment core in the Bay of Bengal (BoB).

We investigated dual carbon isotopes within the vertical water column at sites 67-1 and 67-2 of the western equatorial Indian Ocean to determine the source and age of particulate organic carbon (POC) and thus evaluated the contributions of modern and fossil (aged) POC. The concentration of POC ranged from 7 to 47.3 μgC L−1, δ13CPOC values ranged from -31.8 to -24.4‰, and Δ14CPOC values ranged from -548 to -111‰. Higher values of δ13CPOC and Δ14CPOC near the surface indicated an influence of autochthonous POC, whereas decreasing trends toward the bottom suggested a contribution of aged OC sources to the total POC pool. The contribution of fossil POC was lower near the surface, accounting for only 12% and 6% of the total POC at sites 67-1 and 67-2, respectively; however, in the deeper layers below 1,000 m, the contribution of fossil POC increased to 52% and 44% of the total POC at the two sites. Mechanisms for the increased contributions of fossil OC within deeper POC include the inflow of aged OC from sediments resuspended near slopes, the adsorption of old dissolved organic carbon in deep water masses, and the impact of aged OC that may originate from hydrothermal sources. This study highlights the importance of aged OC in the carbon cycle of the equatorial Indian Ocean.

Blue carbon is fast garnering international interest for its disproportionate contribution to global carbon stocks. However, our understanding of the size of these blue carbon stocks, as well as the provenance of carbon that is stored within them, is still poor. This is especially pertinent for many small-island nations that may have substantial blue carbon ecosystems that are poorly studied. Here, we present a preliminary assessment of blue carbon from three islands in the Maldives. The higher purpose of this research was to assess the feasibility of using blue carbon to help offset carbon emissions associated with Maldivian tourism, the largest Maldivian industry with one of the highest destination-based carbon footprints, globally. We used stable isotope mixing models to identify how habitats contributed to carbon found in sediments, and Loss on Ignition (LoI) to determine carbon content. We found that for the three surveyed islands, seagrasses (Thalassia hemprichii, Thalassodendron ciliatum, Halodule pinofilia, Syringodium isoetifolium, and Cymodocea rotundata) were the main contributors to sediment blue carbon (55 - 72%) while mangroves had the lowest contribution (9 - 44%). Surprisingly, screw pine (Pandanus spp.), a relative of palm trees found across many of these islands, contributed over a quarter of the carbon found in sediments. Organic carbon content ('blue carbon') was 6.8 ± 0.3 SE % and 393 ± 29 tonnes ha-1 for mangrove soils, and 2.5 ± 0.2% and 167 ± 20 tonnes ha-1 for seagrasses, which is slightly higher than global averages. While preliminary, our results highlight the importance of seagrasses as carbon sources in Maldivian blue carbon ecosystems, and the possible role that palms such as screw pines may have in supplementing this. Further research on Maldivian blue carbon ecosystems is needed to: 1) map current ecosystem extent and opportunities for additionality through conservation and restoration; 2) determine carbon sequestration ra

Drops locked inside rock offer clues to modeling Earth's climate and ocean circulation.