All the regular interview rule apply -- speak slowly and clearly, focus on your accomplishments, don't bad mouth your former employers, and wear proper interview clothing. Don't be tempted to wear jeans and a t-shirt because it's "just" a Skpe interview. (And even though it may be tempting to put on a button down shirt and tie on not bother with nice pants, you could get caught and wind up looking foolish, so dress properly from head to toe.)
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