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I actually would debate this list...

TeachersFirst offers this model for elementary (or middle) schools to build skills in reading, writing, speaking, and listening systematically in a schoolwide model including students, teachers, and parents. The free web 2.0 tools suggested here are by no means the only tools that might work. These exemplary tools were chosen by the TeachersFirst Editors for ease of use and versatility in classroom and home use, and could easily be implemented at grade levels other than those suggested here. As students and teachers master a new tool at each grade level, they develop rich literacy skills and vital technology skills, all in the context of reading, writing, speaking and listening across the curriculum.

A great blogpost about using "chat channels" with primary school students but for that matter with any students.