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The oxygen minimum zone has a significant effect on primary production, marine biodiversity, food web structure, and marine biogeochemical cycle. The Arabian Sea oxygen minimum zone (ASOMZ) is one of the largest and most extreme oxygen minimum zones in the world, with a positional decoupling from the region of phytoplankton blooms. The core of the ASOMZ is located to the east of the high primary production region in the western Arabian Sea. In this study, a coupled physical-biogeochemical numerical model was used to quantify the impact of ocean circulation and settling of particulate organic matters (POMs) on the decoupling of the ASOMZ. Model results demonstrate that the increased (decreased) dissolved oxygen replenishment in the western (central) Arabian Sea is responsible for decoupling. The oxygen-rich intermediate water (200-1,000 m) from the southern Arabian Sea enters the Arabian Sea along the west coast and hardly reaches the central Arabian Sea, resulting in a significant oxygen replenishment in the western Arabian Sea high-productivity region (Gulf of Aden) but only a minor contribution in the central Arabian Sea. Besides that, the POMs that are remineralized to consume central Arabian Sea dissolved oxygen comprises not only local productivity in winter bloom but also the transport from the western Arabian Sea high-productivity region (Oman coast) in summer bloom. More dissolved oxygen replenishment in the western Arabian Sea, and higher dissolved oxygen consumption and fewer dissolved oxygen replenishment in the central Arabian Sea could contribute to the decoupling of the ASOMZ and phytoplankton productive zone.

We investigated dual carbon isotopes within the vertical water column at sites 67-1 and 67-2 of the western equatorial Indian Ocean to determine the source and age of particulate organic carbon (POC) and thus evaluated the contributions of modern and fossil (aged) POC. The concentration of POC ranged from 7 to 47.3 μgC L−1, δ13CPOC values ranged from -31.8 to -24.4‰, and Δ14CPOC values ranged from -548 to -111‰. Higher values of δ13CPOC and Δ14CPOC near the surface indicated an influence of autochthonous POC, whereas decreasing trends toward the bottom suggested a contribution of aged OC sources to the total POC pool. The contribution of fossil POC was lower near the surface, accounting for only 12% and 6% of the total POC at sites 67-1 and 67-2, respectively; however, in the deeper layers below 1,000 m, the contribution of fossil POC increased to 52% and 44% of the total POC at the two sites. Mechanisms for the increased contributions of fossil OC within deeper POC include the inflow of aged OC from sediments resuspended near slopes, the adsorption of old dissolved organic carbon in deep water masses, and the impact of aged OC that may originate from hydrothermal sources. This study highlights the importance of aged OC in the carbon cycle of the equatorial Indian Ocean.

Aluminum and manganese are both key parameters in the GEOTRACES program. Data on dissolved aluminum (dAl) and dissolved manganese (dMn) relative to their geochemical behavior remain limited in the northeastern Indian Ocean (IO; including the Bay of Bengal (BoB) and equatorial Indian Ocean (Eq. IO)). Seawater samples collected in the BoB and Eq. IO during the spring inter-monsoon period (7 March to 9 April) of 2017 were analyzed to investigate the behavior and main processes controlling the distributions of dAl and dMn in the northeastern IO. The average concentrations of dAl and dMn in the mixed layer of the BoB were 16.6 and 6.7 nM, respectively. A modified 1-D box-model equation was utilized to estimate the contributions of different sources to dAl and dMn in the mixed layer. Al released from the desorption of and/or dissolution of the lithogenic sediments discharged by the Ganga-Brahmaputra (G-B) river system predominantly controlled the dAl distributions in the mixed layer of the BoB, while the desorption from the lithogenic sediments only contributed approximately 13%-21% dMn. Additional dMn input from the advection of Andaman Sea water and photo-reduction-dissolution of particulate Mn(IV) contributed more than 60% dMn in the mixed layer of the BoB. dAl and dMn in the surface mixed layer of the Eq. IO were mainly affected by the mixing of dAl- and dMn-enriched BoB surface water and low-dAl, low-dMn southern Arabian Sea surface water. Considering water mass properties and dAl concentrations, the distributions of dAl in the intermediate water (750-1,500 m) of northeastern IO were controlled by the mixing of Red Sea Intermediate Water, Indonesian Intermediate Water, and intermediate water of the BoB. Different from dAl, the apparent oxygen utilization relationship with dMn concentrations indicated that the regeneration of lithogenic particles under hypoxic conditions played a more important role than the remineralization of settling organic particles in co

Microplastics pollute most remote and uncharted areas of the ocean.