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Jérôme OLLIER

Soluble Iodine Speciation in Marine Aerosols Across the Indian and Pacific Ocean Basins... - 0 views

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    Iodine affects the radiative budget and the oxidative capacity of the atmosphere and is consequently involved in important climate feedbacks. A fraction of the iodine emitted by oceans ends up in aerosols, where complex halogen chemistry regulates the recycling of iodine to the gas-phase where it effectively destroys ozone. The iodine speciation and major ion composition of aerosol samples collected during four cruises in the East and West Pacific and Indian Oceans was studied to understand the influences on iodine's gas-aerosol phase recycling. A significant inverse relationship exists between iodide (I-) and iodate (IO3-) proportions in both fine and coarse mode aerosols, with a relatively constant soluble organic iodine (SOI) fraction of 19.8% (median) for fine and coarse mode samples of all cruises combined. Consistent with previous work on the Atlantic Ocean, this work further provides observational support that IO3- reduction is attributed to aerosol acidity, which is associated to smaller aerosol particles and air masses that have been influenced by anthropogenic emissions. Significant correlations are found between SOI and I-, which supports hypotheses that SOI may be a source for I-. This data contributes to a growing observational dataset on aerosol iodine speciation and provides evidence for relatively constant proportions of iodine species in unpolluted marine aerosols. Future development in our understanding of iodine speciation depends on aerosol pH measurements and unravelling the complex composition of SOI in aerosols.
Jérôme OLLIER

Previous Shoreline Dynamics Determine Future Susceptibility to Cyclone Impact in the Su... - 0 views

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    Extreme weather events are a cause of mangrove forest loss and degradation globally. Almost half of the world's mangroves are found in the tropical cyclone belt, and forests often experience disturbance in structure, functioning and ecosystem service provision. Understanding the factors that increase the vulnerability of mangroves to such disturbances is a challenge. Using a novel remote sensing analysis combining water class change with vegetation classification, we showed that mangrove loss across multiple cyclone events is influenced by previous erosion history, suggesting that the prior state of the coastline affects susceptibility to future disturbance events. During Cyclone Amphan in May 2020, more than 1,200 km2 of mangroves were damaged and 40.6 km2 of shoreline was lost. Cyclone Amphan caused the most damage out of three recent cyclones, with the most mangrove loss (18.8%) experienced along shorelines that were eroding over the past 35 years. This can be explained by the long-term effect of erosion on the overall intertidal morphology of the shoreline. Landscape-scale mangrove management, particularly of sediment budgets is essential to switch previously eroding mangroves to a state where they can withstand cumulative storm impacts.
Jérôme OLLIER

Quantifying the controlling mineral phases of rare-earth elements in deep-sea pelagic s... - 0 views

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    Recent studies suggest that pelagic sediments can enrich rare-earth elements (REE) acting as a significant reservoir for the global REE budget as well as a potential resource for future exploitation. Although Ca-phosphate (e.g., bioapatite fossils) and Fe-Mn (oxyhydr)oxides (e.g., micronodule) have been considered important REE carriers in deep-sea sediments, the proportion of REE held by each mineral phase remains enigmatic. Here, we have investigated the sediments from two promising REE-rich prospective areas: the Tiki Basin in the Southeast Pacific (TKB) and the Central Indian Ocean Basin (CIOB). The mineral grains including bioapatite fossils and Fe-Mn micronodules have been inspected individually by in-situ microscale analytical methods. Correspondently, the REE bound to Ca-phosphate and Fe-Mn (oxyhydr)oxides have been sequentially extracted and quantified. The crucial role of Ca-phosphate is substantiated by sequential leaching which reveals its dominance in hosting ~69.3-89.4% of total REE. The Fe-Mn (oxyhydr)oxides carry ~8.2% to 22.0% of REE in bulk sediments, but they account for ~70.0-80.5% of Ce owing to their preferential adsorption of Ce over the other REE. Surface sediment on modern seafloor can accumulate high REE contents resulting from the REE scavenging by the host phases within the range of sediment-seawater interface. Differences between TKB and CIOB samples indicate that the REE enrichment in the deep-sea environment may be controlled by multiple factors including the productivity of overlying seawater (e.g., phosphorus flux), water depth relative to carbonate compensation depth (CCD), sedimentation rate, redox condition, and hydrothermal vent input (e.g., Fe-Mn precipitations).
Jérôme OLLIER

Mechanisms of Interannual Variability of Ocean Bottom Pressure in the Southern Indian O... - 0 views

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    The study of ocean bottom pressure (OBP) helps to understand the changes in the sea level budget and ocean deep circulation. In this study, the characteristics and mechanisms of interannual OBP variability in the Southern Indian Ocean are examined using Gravity Recovery and Climate Experiment (GRACE) satellite data from 2003 to 2016. Results show that there are two energetic OBP centers in the Southern Indian Ocean (50°-60°S, 40°-60°E and 45°-60°S, 80°-120°E). The OBP magnitudes at two centers have strong variability on interannual time scales, and their values are larger during austral summer (NDJF) and winter (JJAS). Atmospheric forcing plays an important role in local OBP variability. The high (low) sea level pressure (SLP) over the Southern Indian Ocean benefits positive (negative) OBP anomalies via the convergence (divergence) of Ekman transport driven by local wind. Such SLP anomalies are related to the Southern Annular Mode (SAM), Southern Oscillation (SO) and Indian Ocean dipole (IOD). SAM can influence the OBP changes in both austral summer and winter, while SO and IOD have positive correlations with OBP variability during austral summer and austral winter, respectively. These results are validated by a mass-conservation ocean model, which further confirms the importance of atmospheric forcing on the interannual OBP variations.
Jérôme OLLIER

Inside the Middle East port that the US wants to host aircraft carriers as it pressures... - 0 views

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    Inside the Middle East port that the US wants to host aircraft carriers as it pressures Iran.
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