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Recent studies suggest that pelagic sediments can enrich rare-earth elements (REE) acting as a significant reservoir for the global REE budget as well as a potential resource for future exploitation. Although Ca-phosphate (e.g., bioapatite fossils) and Fe-Mn (oxyhydr)oxides (e.g., micronodule) have been considered important REE carriers in deep-sea sediments, the proportion of REE held by each mineral phase remains enigmatic. Here, we have investigated the sediments from two promising REE-rich prospective areas: the Tiki Basin in the Southeast Pacific (TKB) and the Central Indian Ocean Basin (CIOB). The mineral grains including bioapatite fossils and Fe-Mn micronodules have been inspected individually by in-situ microscale analytical methods. Correspondently, the REE bound to Ca-phosphate and Fe-Mn (oxyhydr)oxides have been sequentially extracted and quantified. The crucial role of Ca-phosphate is substantiated by sequential leaching which reveals its dominance in hosting ~69.3-89.4% of total REE. The Fe-Mn (oxyhydr)oxides carry ~8.2% to 22.0% of REE in bulk sediments, but they account for ~70.0-80.5% of Ce owing to their preferential adsorption of Ce over the other REE. Surface sediment on modern seafloor can accumulate high REE contents resulting from the REE scavenging by the host phases within the range of sediment-seawater interface. Differences between TKB and CIOB samples indicate that the REE enrichment in the deep-sea environment may be controlled by multiple factors including the productivity of overlying seawater (e.g., phosphorus flux), water depth relative to carbonate compensation depth (CCD), sedimentation rate, redox condition, and hydrothermal vent input (e.g., Fe-Mn precipitations).

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The recently discovered Onnuri hydrothermal vent field (OVF) is a typical off-axis ultramafic-hosted vent system, located on the summit of the dome-like ocean core complex (OCC) at a distance of ∼12 km from the ridge axis along the middle region of the Central Indian Ridge (CIR). The plume chemistry with high methane anomaly was consistent with the precursor of hydrothermal activity; however, the fundamental characteristic of the OVF system, such as the hydrothermal circulation process and source of heat, remains poorly understood. Here, we focus on the geochemical features of surface sediments and minerals collected at and around the OVF region in order to better understand this venting system. The results reveal that the OVF sediments are typified by remarkably high concentrations of Fe, Si, Ba, Cu, and Zn, derived from hydrothermal fluid and S and Mg from seawater; depleted C-S isotope compositions; and abundant hydrothermally precipitated minerals (i.e., Fe-Mn hydroxides, sulfide and sulfate minerals, and opal silica). Notably, the occurrence of pure talc and barite bears witness to strong hydrothermal activity in the OVF, and their sulfur and strontium isotope geochemistry agree with extensive mixing of the unmodified seawater with high-temperature fluid derived from the gabbroic rock within the ultramafic-dominated ridge segment. The findings reveal that the OVF is a representative example of an off-axis, high-temperature hydrothermal circulation system, possibly driven by the exothermic serpentinization of exposed peridotites. Given the widespread distribution of OCC with detachment faults, furthermore, the OVF may be the most common type of hydrothermal activity in the CIR, although the paucity of data precludes generalizing this result. This study provides important information contributing to our understanding of the ultramafic-hosted hydrothermal vent system with a non-magmatic heat source along mid-ocean ridges.

Aluminum and manganese are both key parameters in the GEOTRACES program. Data on dissolved aluminum (dAl) and dissolved manganese (dMn) relative to their geochemical behavior remain limited in the northeastern Indian Ocean (IO; including the Bay of Bengal (BoB) and equatorial Indian Ocean (Eq. IO)). Seawater samples collected in the BoB and Eq. IO during the spring inter-monsoon period (7 March to 9 April) of 2017 were analyzed to investigate the behavior and main processes controlling the distributions of dAl and dMn in the northeastern IO. The average concentrations of dAl and dMn in the mixed layer of the BoB were 16.6 and 6.7 nM, respectively. A modified 1-D box-model equation was utilized to estimate the contributions of different sources to dAl and dMn in the mixed layer. Al released from the desorption of and/or dissolution of the lithogenic sediments discharged by the Ganga-Brahmaputra (G-B) river system predominantly controlled the dAl distributions in the mixed layer of the BoB, while the desorption from the lithogenic sediments only contributed approximately 13%-21% dMn. Additional dMn input from the advection of Andaman Sea water and photo-reduction-dissolution of particulate Mn(IV) contributed more than 60% dMn in the mixed layer of the BoB. dAl and dMn in the surface mixed layer of the Eq. IO were mainly affected by the mixing of dAl- and dMn-enriched BoB surface water and low-dAl, low-dMn southern Arabian Sea surface water. Considering water mass properties and dAl concentrations, the distributions of dAl in the intermediate water (750-1,500 m) of northeastern IO were controlled by the mixing of Red Sea Intermediate Water, Indonesian Intermediate Water, and intermediate water of the BoB. Different from dAl, the apparent oxygen utilization relationship with dMn concentrations indicated that the regeneration of lithogenic particles under hypoxic conditions played a more important role than the remineralization of settling organic particles in co

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