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DRIVER-MATERIALS-INFRASTRUCTURE Municipal pipe market spending makes up 30 percent of overall utility CAPEX for water infrastructure. In part, to address aging pipes, bursts, and other leakage management issues, the pipe market is turning to new materials (plastic) and new technologies (trenchless). More than $234 billion (USD) of capital expenditures (CAPEX) are forecasted over the next decade to address aging municipal water and wastewater pipe network infrastructure, according to Bluefield's forecasts. Precipitated by decades of underinvestment, municipal utilities are under increasing pressure to address deteriorating linear assets at a faster pace. Water losses through leaks for U.S. utilities average 15 percent annually, with some cities, towns, and communities losing more than half of all water pumped and treated for distribution to customers. As a result, rehabilitation of existing pipes is the fastest growing spend category, increasing annually from $253 million in 2019 to $576 million by 2028. Network expansions, particularly in high population growth across the sunbelt states (e.g. Texas and Arizona), will drive the lion's share of spending on new build.

DRIVERS-TREATMENT-TTHM-POLLUTION-SCARCITY-FUNDING Disinfection by-products (DBP) are a class of chemical by-products also referred to as trihalomethanes (THMs), formed when chlorine or bromine interacts with the natural organic materials found in water. DBPs also include other formed products, such as haloacetic acids, haloacetonitriles, haloketones, and chlorophenols. The composition and levels of specific DBPs are determined by water quality, water treatment conditions, and disinfectant type (IPCS, 2000). Primary sources of DBPs are chlorinated drinking water and recreational water bodies, such as swimming pools. In drinking water, trichloromethane is the predominant DBP, usually found at much higher levels than bromodichloromethane; tribromomethane is the least abundant (Krasner et al., 1989). DBPs are volatile at room temperature and can be detected in ambient air during activities such as showering, bathing, dishwashing, and swimming (Backer, et al., 2000; Gordon et al., 2006). Trichloromethane has industrial applications and is used to produce refrigerants and feedstock. It may be released into the environment where chlorine-based chemicals are used for bleaching and disinfecting processes or disposed at hazardous waste sites (IPCS, 2004; LaRegina, et al. 1986). Tribromomethane has limited industrial uses, mainly in geological assaying, electronics manufacturing, and as a solvent in laboratory analyses (ATSDR, 2005). DBPs tend not to bioaccumulate in aquatic organisms or persist in open or surface waters or soils, but they can remain in water within closed pipe systems. Workplace exposure may occur during the production of trichloromethane or tribromomethane, or in workplaces where DBPs may be generated, such as pulp or paper manufacturing, swimming pools, and water treatment plants (IPCS, 2004).

DRIVERS-POLLUTION-TREATMENT-SCARCITY-INFRASTRUCTURE Total trihalomethanes (TTHM) are a group of disinfection byproducts that form when chlorine compounds that are used to disinfect water react with other naturally occurring chemicals in the water. They are colorless, and will evaporate out of the water into the air. There are four significant TTHM potentially found in disinfected drinking water and their combined concentration is referred to as total TTHM. Levels of TTHM generally increase in the summer months due to the warmer temperatures, but can also be affected by seasonal changes in source water quality or by changing amounts of disinfection added. Water systems often can experience temporary increases in TTHM due to short-term increases in chlorine disinfection. Chlorine disinfection increases can occur when there is a water main break, when water systems are under repair, or when there is a potential microbial (example: bacteria) problem or threat.

DRIVER-TTHMs-POLLUTION-PURITY-INFRASTRUCTURE-TREATMENT Trihalomethanes (THMs) are the result of a reaction between the chlorine used for disinfecting tap water and natural organic matter in the water. At elevated levels, THMs have been associated with negative health effects such as cancer and adverse reproductive outcomes. Now a study by government and academic researchers adds to previous evidence that dermal absorption and inhalation of THMs associated with everyday tap water use can result in significantly higher blood THM concentrations than simply drinking the water does [EHP 113:863-870]. The results of this exposure assessment study could serve as a guide for future epidemiologic investigations exploring the potential connection between THMs in tap water and adverse health effects.

Here are 12 critical facts about TTHM as the city's fight to reduce it continues: 1. Trihalomethanes are actually a group of four chemicals that are formed along with other disinfection byproducts when chlorine reacts with organic materials such as leaves or dirt in water, according to the U.S. Environmental Protection Agency. 2. TTHMs are odorless and colorless, according to the Michigan Department of Environmental Quality. That means the high levels of TTHM in Flint water last year are not related to problems such as discoloration and odor in tap water. 3. The four trihalomethane chemicals are chloroform, bromodichloromethane, dibromochloromethane and bromoform. 4. U.S. EPA regulates TTHM at a maximum allowable, annual, average level of 80 parts per billion. The standard has been in place since December 2001 for large public surface water systems and since December 2003 for small surface water and all groundwater systems. 5. Four of eight testing sites in Flint averaged more than the acceptable limit of 80 parts per billion of TTHM last year. 6. Testing for TTHM is done on a quarterly basis, which means that people who use the system are exposed to water for several months before public notice is required. That's because TTHM is a chronic -- not immediate --health threat, according to the DEQ. 7. U.S. EPA estimates the 80 parts per billion standard prevents an estimated 280 cases of bladder cancer each year out of a total of more than 330 million people who use public water supplies nationwide. 8. Since it started using the Flint River as its water source, three quarterly tests have produced these TTHM results in the city: 15 samples have been above the TTHM threshold. Nine samples have tested at less than 80 parts per billion. 9. The most recent quarterly test showed just one site of eight that was above the 80 parts per billion threshold. And a voluntary test of the same sites in late January by the city were all within were all within the limits. 10. The testin

DRIVER-FLINT-TREATMENT-WATER-POLLUTION-CHEMISTRY Former EPA Drinking Water Standards Director, Dr. Joseph Cotruvo developed the US Environmental Protection Agency's (EPA's) first THM Rule in 1979. I spoke with him for his perspective on TTHM in Flint's drinking water: "Scientists have studied the health effects of disinfection byproducts extensively. For example, the January 4, 2006 Federal Register,2 which announced the Stage 2 Rule, cites over 60 mixed result research studies probing the potential health effects of exposure to disinfection byproducts such as TTHM. After reviewing many studies, the Agency concluded that 'no dose response relationship or causal link has been established between exposure to chlorinated drinking water or disinfection byproducts and adverse developmental or reproductive effects.' Nevertheless, EPA takes a very precautious stand, saying the studies 'do provide an indication of a potential health concern that warrants incremental regulatory action beyond Stage 1 DBPR [Disinfectants and Disinfection Byproducts Rule].'"

DRIVER-TREATMENT-TTHM-POLITICAL CLASS-ACTION LAWSUIT Rapid detection of the total trihalomethanes (TTHM) in treated drinking water is essential for compliance with the Environmental Protection Agency's (EPA) Stage 2 Disinfectants and Disinfection Byproducts (DBP) Rule, which limits the maximum contaminant level of TTHM in drinking water. The current detection method for TTHM determination involves sending samples to EPA certified laboratories for gas chromatography analysis; a method that is both expensive and time consuming. In the Phase I, Agave BioSystems demonstrated proof of concept for a sensitive colorimetric TTHM detection system based on a modified Fujiwara reaction, which can be integrated into a portable field sensor. This assay system utilizes a modified Fujiwara reaction to yield a detectable color product that correlates directly to the TTHM levels of the water sample. In this Phase II, Agave BioSystems proposes to construct a compact and portable rapid response TTHM water monitoring system for field use. BENEFIT: TTHM is linked to increased rates of bladder and colorectal cancers, and several studies link TTHM to heart, liver, and central nervous system damage. The EPA estimates that lowering TTHM levels in as few as 1,200 small drinking water systems could prevent up to 20 cases of bladder cancer per year, resulting in economic benefits of up to $110 million per year. Another documented health risk is the increased rate of miscarriage and congenital birth defects in areas with high TTHM levels. A Virginia based class action lawsuit seeking more than $1 billion in damages, claims that peak TTHM occurrences in one water distribution system may have led to multiple miscarriages. A cost effective and easy to use field portable sensor, such as the one proposed by Agave BioSystems, would enable drinking water delivery systems of any size to effectively monitor the levels of TTHM in their water supply on a more frequent basis, and allow proactively treating

DRIVER-PUBLICNOTICE-TTHM-TREATMENT When a PWS exceeds the maximum contaminant level (MCL) for both Total Trihalomethanes (TTHM) and Haloacetic Acids (HAA5) it must issue a public notice to inform the consumers of its water that the levels of Total Trihalomethanes and Haloacetic Acids detected in their water have exceeded the MCLs set by Federal Regulations. You can use this template as a guide to prepare that public notice

DRIVER-WATER-SCARCITY-INFRASTRUCTURE-MATERIALS The North American drinking water infrastructure network spans an estimated 1 million miles, more than four times longer than the National Highway System, and that doesn't even take wastewater pipes into account. Much of the water infrastructure in the United States will need to be replaced in the next three decades. A large portion of water pipes was installed during three periods, and they will all need to be replaced in the next 25 years. Consider the following The oldest cast iron pipes laid in the late 1800s usually last 120 years; Pipes laid in 1920s must be replaced after 100 years; Pipes from the post-World War II boom wear out after 75 years. According to a 2012 report done by the American Water Works Association, the cost estimate to replace the old pipes is approximately $1 trillion over the next 25 years. The longer our water infrastructure is out of sight and out of mind, the closer we are to a serious national situation that will require immediate and dramatic funding. The cost of water infrastructure replacement far exceeds the financial capabilities of local water utilities and requires a strong commitment from not only utilities but rate-payers and government as well.

DRIVER-TREATMENT-WATER-INFRASTRUCTURE-CHEMISTRY-CHLORAMINE One new option that communities with ammonia problems have is biological filtration. This is a safe, chemical-free, method of removing ammonia. In a biological filtration facility, one of the stages of filtration is to pass the water through a special filter that is full of nitrifying bacteria. These bacteria take in the ammonia and some oxygen and perform a bio-oxidation reaction. They oxidize the ammonia into nitrite NH3 + O2 -> NO2- + 3H+ Then further oxidize that into nitrate, NO2- + H2O -> NO3- + 2H+. The bacteria gain energy from these reactions and are specialized to do them very efficiently. This process is part of the natural nitrogen cycle and does not produce any harmful byproducts. The nitrate that is produced by this process can easily be removed from the water by the reverse osmosis membrane in the final stage of the filtration process. The reaction between chlorine and ammonia can be written as NH3 +HOCl -> NH2Cl + H2O. In this chemical equation, NH3 is ammonia and HOCl is hypochlorous acid which is formed when the chlorine is first dissolved in the water. The primary result of this chemical reaction is NH2Cl, a chemical known as chloramine. Chloramine is a disinfectant like chlorine, it is a weaker disinfectant than chlorine but it lasts much longer in water. The chlorine concentration in water can gradually decrease as the chlorine evaporates out but chloramine does not do this. This makes it useful for making sure water stays disinfected throughout drinking water distribution systems. In areas where there is no, or very little, ammonia in the raw water treatment facilities might still want to use chloramine for this purpose. After chlorinating (disinfecting) the water, as the last step in the treatment process, they add ammonia and more chlorine to the water so that they react and create chloramine.