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Another tiny miracle: Graphene oxide soaks up radioactive waste - 0 views

  • Graphene oxide has a remarkable ability to quickly remove radioactive material from contaminated water
  • A collaborative effort by the Rice lab of chemist James Tour and the Moscow lab of chemist Stepan Kalmykov
  • microscopic, atom-thick flakes of graphene oxide bind quickly to natural and human-made radionuclides and condense them into solids
  • ...24 more annotations...
  • flakes are soluble in liquids and easily produced in bulk
  • The discovery
  • could be a boon in the cleanup of contaminated sites like the Fukushima nuclear plants
  • could also cut the cost of hydraulic fracturing ("fracking") for oil and gas recovery and help reboot American mining of rare earth metals
  • Graphene oxide's large surface area defines its capacity to adsorb toxins
  • high retention properties are not surprising
  • What is astonishing is the very fast kinetics of sorption, which is key
  • the collaboration took root when
  • a graduate student
  • graduate student in Kalmykov's group, met at a conference several years ago.
  • researchers focused on removing radioactive isotopes of the actinides and lanthanides – the 30 rare earth elements in the periodic table – from liquids, rather than solids or gases
  • Naturally occurring radionuclides are also unwelcome in fracking fluids that bring them to the surface in drilling operations
  • When groundwater comes out of a well and it's radioactive above a certain level, they can't put it back into the ground
  • Companies have to ship contaminated water to repository sites around the country at very large expense
  • The ability to quickly filter out contaminants on-site would save a great deal of money
  • even greater potential benefits for the mining industry
  • Environmental requirements have "essentially shut down U.S. mining of rare earth metals, which are needed for cell phones
  • China owns the market because they're not subject to the same environmental standards
  • this technology offers the chance to revive mining here, it could be huge
  • capturing radionuclides does not make them less radioactive, just easier to handle
  • Where you have huge pools of radioactive material, like at Fukushima, you add graphene oxide and get back a solid material from what were just ions in a solution
  • Then you can skim it off and burn it
  • Graphene oxide burns very rapidly and leaves a cake of radioactive material you can then reuse
  • The low cost and biodegradable qualities of graphene oxide should make it appropriate for use in permeable reactive barriers, a fairly new technology for in situ groundwater remediation,
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