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You can delegate access to your Gmail to another person so they can read, send, and delete messages on your behalf. For example, you can delegate e-mail rights to an admin in your organization, or you could delegate your personal email access to your spouse. The delegate can also access the other person's contacts by clicking the Contacts link. Clicking the To, Cc, or Bcc links in the mail compose window will also bring up your contacts

This is the main page for Google Apps Administrator Help. Lots of good stuff here on setting up and configuring domains.

GoogleApps YouTube channel. Great resources for domain admins & users.