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Saad Shaik

Gale Science In Context - Document - 0 views

  • Ammonia
    • Saad Shaik
       
      NH3
  • Ammonia (uh-MOH-nyah) is a colorless gas with a strong, suffocating odor.
    • Saad Shaik
       
      qualitative descriptors
  • Ammonia was the first chemical compound to be found in interstellar space, the space between stars.
    • Saad Shaik
       
      how cool
  • ...7 more annotations...
  • About 90 percent of all the ammonia used in the United States goes to the production of fertilizers.
    • Saad Shaik
       
      thats a lot of percent
  • (400°C to 650°C; 750°F to 1200°F) and pressure (200 to 400 atmospheres; 3,000 to 6,000 pounds per square inch) over a catalyst made of finely-divided iron.
    • Saad Shaik
       
      maximize the amount of ammonia produced
  • The Haber-Bosch process remains the most common form of ammonia production in many countries, including the United States.
    • Saad Shaik
       
      it works the best
  • Ammonia is used in a variety of forms as a fertilizer.
    • Saad Shaik
       
      more fertilizer
  • In addition to its use in the manufacture of fertilizers and explosives, smaller amounts of ammonia are used: As a refrigerant; In the manufacture of plastics; As a raw material in the manufacture of other nitrogen-containing chemicals; In the production of dyes; As a rocket fuel; For the neutralization of acids during the refining of petroleum; In order to produce specialized types of steel; and As a nutrient in yeast cultures in food processing operations.
    • Saad Shaik
       
      uses of ammonia
  • The next largest use of ammonia is in the synthesis of nitric acid (HNO3). In a process developed by the German chemist Wilhelm Ostwald (1853–1932), ammonia, oxygen, and water are reacted together in a series of steps that results in the formation of nitric acid. Nitric acid, the thirteenth most important chemical in the United States in terms of productions, has a number of important uses, including the manufacture of explosives. Like the Haber-Bosch process, the Ostwald process contributed to the success experienced by Germany during World War I.
    • Saad Shaik
       
      ammonia is also used for explosives
  • Both gaseous and liquid ammonia pose moderate health hazards to those who come into contact with them. For example, farmers who handle liquid ammonia risk the possibility of painful blistering of the skin or damage to the mucous membranes if they come into contact with the ferilizer. Ammonia fumes can irritate the mouth, nose, and throat, causing coughing and gagging responses. Higher levels of exposure may irritate the lungs, resulting in shortness of breath and producing headaches, nausea, and vomiting. Very high exposures can cause a buildup of fluid in the lungs that can result in death. Since ammonia is a common ingredient of many household products, everyone should be aware of its health risks, although the threat posed by such products is, in fact, very small.
    • Saad Shaik
       
      negative side affects of ammonia, but only occur if mishandled
  •  
    A document about properties of Ammonia
Anastasia Georginis

Gale Science In Context - Document - 17 views

  • Ammonia
    • Mrs. Byrge
       
      NH3
  • Skip to Content Change Resources Return to My Library " function addWindowLoadEvent(func) { jQuery(document).ready(func); }
  • action of steam on calcium cyanamide, called the cyanamide process
    • Pulvender Rishika
       
      what is cyanamide; like what chemicals in addition to cyanide?
    • Mrs. Byrge
       
      an amide is an organic chemical with CN in it - you will learn more about them next year during our orgo unit
  • ...12 more annotations...
  • a sharp-smelling, flammable, and toxic gas that is very soluble in water
    • Anastasia Georginis
       
      physical properties of ammonia
  • Joseph Priestley
    • Yashas Vaidya
       
      The first person to experiment with amonia
  • hydrogen bonding
    • Pulvender Rishika
       
      strongest type of bonding; even among ionic bonding.
    • Vikrant Garg
       
      A hydrogen bond is not a bond. It's in IMF. It's the strongest IMF.
    • Mrs. Byrge
       
      good catch vikrant :)
  • The Haber-Bosch process is the basis for modern ammonia production
    • Yashas Vaidya
       
      The purpose of the haber process
    • faiyza osman
       
      a higher temperature would help yield more product
  • iron catalyst
    • Pulvender Rishika
       
      how can you tell whether it is an iron catalyst? or homo or hetero?
    • Mrs. Byrge
       
      Since it is iron, a solid and reactants are gasses, it is heterogeneous.
  • structure and mode of action are imperfectly understood
    • Pulvender Rishika
       
      very few processes can be "perfectly" understood. with a changing world, all factors are changing in parallel
  • High pressure conditions
    • faiyza osman
       
      High pressure conditions would allow the equilibrium to shift in favor of ammonia, the side w/less moles, but it would not change Kc
  • corn, wheat, and soybeans.
    • Pulvender Rishika
       
      all subjects and fields are inter-related. agriculture's highest yields come from the production of corn, wheat, and soybeans and yet a chemical compound, ammonia can be traced back to it.
    • faiyza osman
       
      is there controversy surrounding the uses of ammonia in fertilizers in order to increase the yield of crops? Are there negative effects?
  • Ostwald process
    • Pulvender Rishika
       
      from haber process, to Ostwald process, improvements and methods continue to be developed and knowledge continues to expand infinitely.
    • Anastasia Georginis
       
      is this related to Haber and Contact Processes?
  • much milder conditions than those of the Haber-Bosch process
    • Anastasia Georginis
       
      probably not as effective in creating NH3 though
  • temperatures
    • Pulvender Rishika
       
      stessor of Le Chatlier's and factor that can affect rate of reaction
  •  
    For in class annotating
Mrs. Byrge

Gale Science In Context - Document - 9 views

  • reaction of hydrogen with nitrogen in the presence of an iron catalyst,
    • Marvin Shih
       
      use of catalyst
    • jeet shah
       
      The iron catalyst is simply used to speed up BOTH the forward and reverse reactions. It does not change the magnitude or state of either reaction
  • the Haber-Bosch process.
    • Rajmund Niwinski
       
      This is the process by which ammonia is industrially made
  • Ammonia (boiling point -28.03°F [-33.35°C])
    • Chennupati Surya
       
      Ammonia is a Gas at room temperature
    • Ngo Thien Quy
       
      Since Ammonia has such a low boiling point of -28.03 degrees Farenheit, it provides insight as to why ammonia is a gas at room temperature.
    • Dhatri Nandyala
       
      Why does ammonia have such low boiling point?
    • Ngo Thien Quy
       
      Ammonia has such a low boilling point because of the properties of the bonds and the elements that it is composed of.
  • ...61 more annotations...
  • Urea eventually reacts with water to form ammonia
    • Rajmund Niwinski
       
      Could this be used to produce usable ammonia?
    • Vikrant Garg
       
      Probably; however, this process may be too painstaking to ever be rendered effective. 
    • Mrs. Byrge
       
      and not very cost effective.
  • High pressure conditions (150-250 bar) are used, and temperatures range from 752-932°F (400-500°C).
    • Marvin Shih
       
      specific conditions used
    • Chennupati Surya
       
      A moderately high temperature is used even though the process is exothermic because the rate cannot be slowed down too much or else the process will take too long and profits will be lost.
  • reacting calcium carbide with nitrogen at high temperatures
    • OB Rahim
       
      CaC2 + N2 → CaCN2 + C
    • OB Rahim
       
      CaC2 + N2 → CaCN2 + C
  • The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated.
  •  The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated
  • The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated
  •      The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated .
  • The
    • Dhanushya Battepati
       
      ammonia can act as a base and acid
  • Ammonia is manufactured by the 1reaction of hydrogen with nitrogen in the presence of an iron catalyst, which is known as 1the Haber-Bosch process. The reaction is exothermic and is accompanied by a concentration in volume. (The ammonia occupies less volume than the gases from which it is made.) High pressure conditions (150-250 bar) are used, and temperatures range from 752-932°F (400-500°C).
  • Ammonium hydroxide exhibits the characteristics of a weak base
    • Yashas Vaidya
       
      characteristics of ammonia
  • The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated
    • Japnam Jassal
       
      Circulation of reactants
  • A recent toxic substance inventory done by the United States government estimated that in 1989, 200,000 tons of ammonia were released into the environment.
    • Rajmund Niwinski
       
      This raises the question of the extent to which we should be controlling production of pollutants; in this case, it is ammonia.
    • Aditya Yelamanchi
       
      I think that we should be more careful with how much ammonia we produce.
  • The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated
    • Japnam Jassal
       
      Circulation of the reactants
  • high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
    • Akansha A
       
      Catalyst speeds reaction while pressure pushes forward reaction (equilibrium shifts to the right)
  • It also has the ability to dissolve cellulose, and has been used in the process for making regenerated cellulose fibers, or rayon
    • Dhatri Nandyala
       
      another purpose of copper(II) ammonia complex
  • Ammonium salts of oxidizing anions--nitrate, dichromate, and perchlorate--are unstable and can explode or deflagrate when heated
    • Ngo Thien Quy
       
      Ammonia is NH3, but ammonium NH4. I believe the structure of ammonia is trigonal pyramidal and then ammonium has a structure of tetrahedral.
  • German chemists Fritz Haber and Carl Bosch learned how to make ammonia in large quantities by high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
    • Kobir Hussain
       
      optimized reaction using Le Chatelier's Principle
  • World ammonia production is about 100 million tons per year, which amounts to about 40 pounds (18 kg) for each person on Earth.
    • OB Rahim
       
      Do we really need this much?
    • Yashas Vaidya
       
      yes
    • Rajmund Niwinski
       
      Most probably not.
    • Ngo Thien Quy
       
      I do not necessarily think we "need" the ammonia produced. Ammonia's largest role is being part of, or being, a fertilizer. Ammonia reacts well with what is in the soil, and ammonia would provide nutrients once it breaks down.
  • The gases that enter the catalytic converter must be highly purified and free of sulfur compounds, which adversely affect the catalyst
    • jeet shah
       
      Why must it be free of sulfur compounds? How does it affect the catalyst?
    • Rajmund Niwinski
       
      I'm guessing that the Sulfur compounds would react with the Iron catalyst, thus lowering its efficiency.
    • Dhatri Nandyala
       
      How do even the sulfur compounds come in the process?
    • Mrs. Byrge
       
      Yep, you'll get a layer of iron sulfide on the outside of the iron - so iron will not be able to act at catalyst.
  • lime
    • Kobir Hussain
       
      What is lime?
    • Mrs. Byrge
       
      CaO
    • Japnam Jassal
       
      CaO
    • Kobir Hussain
       
      Thank you for telling me.
    • Rajmund Niwinski
       
      It's a general term for inorganic compounds that contain calcium
  • United States production of ammonia reached 17 million tons in 1991, and demand was even larger than U.S. production, leading to about two million tons of imports. World ammonia production is about 100 million tons per year, which amounts to about 40 pounds (18 kg) for each person on Earth.
    • Kaeley McGrane
       
      What conditions explain why the US, (one country, large but not the largest) is using almost 20% of the world's industrial prodution of ammonia? Is this justified?
  • It is often found that considerable heat is absorbed when ammonium salts dissolve in water, leading to dramatic reduction in temperature.
    • Dhatri Nandyala
       
      Thus it is endothermic
  • the 1
  • It is often found that considerable heat is absorbed when ammonium salts dissolve in water, leading to dramatic reduction in temperature.
    • Akansha A
       
      Endothermic reactions of ammonium salts and H2O
  • free electrons can be obtained by treating sodium/ammonia solutions with complexing agents.
  • hydrogen treatment of magnetite
  • A large ammonia plant might have as much as 100 tons of catalyst.
    • Ngo Thien Quy
       
      If the ammonia plant has such a large amount of catalyst, the reaction of creating and decomposing ammonia would be ongoing and occur much more quickly compared to how it would've reacted without a catalyst.
    • Kaeley McGrane
       
      This would also imply that, economically, the use of a catalyst increases the efficiency of the reaction by so much that the cost of 100 tons of catalyst is equal to or less than the money saved by speeding up this reaction
  •  free electrons can be obtained by treating sodium/ammonia solutions with complexing agents.
  • The largest use of ammonia is in fertilizers, which are applied to the soil and help provide increased yields of crops such as corn, wheat, and soybeans. Liquid ammonia, ammonia/water solutions, and chemicals made from ammonia, such as ammonium salts and urea, are all used as sources of soluble nitrogen. Urea, which is made from ammonia and carbon dioxide, can also be used as a feed supplement for cattle, aiding in the rapid building of protein by the animals.
    • jeet shah
       
      It seems that as time progresses, scientists are finding more and more ways to use ammonia.
  • These molecules continually undergo a type of motion called inversion, in which the nitrogen atom passes through the plane of the three hydrogen atoms like an umbrella turning inside out in the wind
    • Kaeley McGrane
       
      This is really interesting, but what causes this inversion?
    • Mrs. Byrge
       
      movement of electrons
  • Urea, which is made from ammonia and carbon dioxide, can also be used as a feed supplement for cattle
    • Dhanushya Battepati
       
      used for fertilizers
  • ammonia is formed and removed, and the unconverted reactants are recirculated.
    • Kobir Hussain
       
      Ammonia removed to push reaction forward.
  • The reaction is exothermic
    • Akansha A
       
      If the reaction is exothermic, why is such a high temperature used to produce more ammonia?
    • Mrs. Byrge
       
      catalyst works better at higher temperature
  • Nitric acid and nitrates are needed for the manufacture of explosives like TNT, nitroglycerin, gunpowder, and also for the propellants in cartridges for rifles and machine guns.
    • Aditya Yelamanchi
       
      Should scientists be held responsible for their developments of weapons?
  • nitroglycerin, gunpowder, and also for the propellants in cartridges for rifles and machine guns.
  • neutralizing acids with the formation of ammonium salts
    • jeet shah
       
      How can you neutralize acids?
    • Mrs. Byrge
       
      with a base
  • The largest use of ammonia is in fertilizers
    • Yashas Vaidya
       
      the purpose of amonia
  • bar of pressure
    • Ngo Thien Quy
       
      what is the unit bar of pressure?
  • The gases that enter the catalytic converter must be highly purified and free of sulfur compounds,
  • Because of its basic properties, ammonia is able to react with acidic gases such as nitrogen oxides and sulfur oxides to form ammonium salts. Thus
    • Dhatri Nandyala
       
      Ammonia has multiple purposes because of its chemical properties
  • oxidation of ammonia
  • 1 bar of pressure
  • where it acts as a base in its chemical reactions.
    • Adi Gill
       
      pH greater than 7
    • jeet shah
       
      Hello Adi please to meet you. So my impression from the article is that it is amphoteric...it just depends on the situation. Do you agree?
  • oxidation of ammonia
  • Because of its basic properties, ammonia is able to react with acidic gases such as nitrogen oxides and sulfur oxides to form ammonium salts
    • Chennupati Surya
       
      This is why we need so much annually
  • oxidation of ammonia
  • oxidation of ammonia
  • oxidation of ammonia
  • oxidation of ammonia
  • although much controversy exists over the details
    • Adi Gill
       
      different people believe different things
  • Ostwald process
    • Ngo Thien Quy
       
      our class is going to learn about the Ostwald process, like read about it, correct?
    • Kobir Hussain
       
      ask Mrs. Byrge
  • oxidation of ammonia
  • DuPont Chemical Co
  • oxidation of ammonia
  • oxidation of ammonia
    • Japnam Jassal
       
      Removal of electron and hydrogen and gain oxygen
  • New uses may develop, particularly for ammonia as a relatively inexpensive base with unique properties
    • Kobir Hussain
       
      Ammonia is good for innovation
  • ) proved that ammonia is composed of nitrogen and hydrogen.
    • Adi Gill
       
      N2 + 3H2 ---> 2NH3
  • ammonia is composed of nitrogen and hydrogen.
    • jeet shah
       
      Decomposition rxn.
  • Further energy is needed to produce the hydrogen from hydrocarbon feedstocks and to separate nitrogen from air.
    • Aditya Yelamanchi
       
      Could we use this to produce energy by lets saying heating water?
Marvin Shih

Gale Science In Context - Document - 2 views

  • The Haber-Bosch process was developed largely because of Germany's need for explosives in World War I. Ammonia gas is converted to nitric acid, which, in turn, is used in making sodium and potassium nitrate, major components of explosives. Fritz Haber believed that it was his patriotic duty to contribute to the German war effort in whatever way he could, which led to his development of a new method for making ammonia.
    • Marvin Shih
       
      the Haber-Bosch Process was developed for explosives production during war, but is also in peaceful applications like agriculture/farming.
    • Vikrant Garg
       
      controversy: is the process more good than bad? It has both good and bad uses. Even fertilizer created from ammonia is not very healthy for the water levels from runoff. 
    • Marvin Shih
       
      tool for either purpose: fertilizer for food/sustaining life, or for its destruction
  • CATALYST A material that increases the rate of a chemical reaction without undergoing any change in its own chemical structure.
    • Marvin Shih
       
      catalyst use
  • Very soluble in cold water; soluble in alcohol, ether, and many organic solvents
    • Marvin Shih
       
      why is it so soluble? molecular structure?
  • ...7 more annotations...
  • Ammonia is used in a variety of forms as a fertilizer. It can be liquified or dissolved in water and sprayed on land, or it can be converted into any one of a number of compounds, such as ammonium nitrate, ammonium phosphate, or ammonium sulfate.
  • 200 to 400 atmospheres
  • nitrogen and hydrogen. The two gases are combined with each other at high temperature (400°C to 650°C; 750°F to 1200°F)
    • Marvin Shih
       
      Involves nitrogen and hydrogen, high temperature increases rate of rxn so there is a yield
  • pressure (200 to 400 atmospheres
    • Marvin Shih
       
      2 atm or 200 atm?
  • Ammonia (uh-MOH-nyah) is a colorless gas with a strong, suffocating odor
  • About 90 percent of all the ammonia used in the United States goes to the production of fertilizers.
  • Both gaseous and liquid ammonia pose moderate health hazards to those who come into contact with them.
vinaireddy123

Gale Science In Context - Document - 1 views

  • is a sharp-smelling, flammable, and toxic gas that is very soluble in water, where it acts as a base in its chemical reactions
    • vinaireddy123
       
      characteristics of Ammonia
  • may have been the source of nitrogen for the earliest forms of life
  • n liquid or frozen ammonia, the molecules attract one another through sharing a hydrogen atom between one molecule and the next, called hydrogen bonding.
  • ...1 more annotation...
  • When dry, this substance is so sensitive that the lightest touch will cause it to explode with a crackling sound and a puff of purple iodine vapor.
    • vinaireddy123
       
      Interesting....
Miral Tripathi

Gale Science In Context - Document - 0 views

  • ammonium compounds were used in rites honoring the god Ammon
    • Miral Tripathi
       
      The uses of Ammonia during ancient times
  • three parts hydrogen and one part nitrogen
    • Miral Tripathi
       
      NH3 learned from last year
  • German chemists Fritz Haber and Carl Bosch learned how to make ammonia in large quantities by high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
    • Miral Tripathi
       
      Origins of the Haber-Bosch process
  • ...2 more annotations...
  • Ammonium hydroxide exhibits the characteristics of a weak base, turning litmus paper blue, and neutralizing acids with the formation of ammonium salts.
    • Miral Tripathi
       
      properties of ammonium hydroxide
  • In liquid or frozen ammonia, the molecules attract one another through sharing a hydrogen atom between one molecule and the next, called hydrogen bonding. In this attraction, called association, compounds apparently containing free electrons can be obtained by treating sodium/ammonia solutions with complexing agents.
    • Miral Tripathi
       
      Bonding properties
Shirley Lu

Gale Science In Context - Document - 2 views

  • are water soluble and volatile when heated.
  • Ammonia is a flammable gas and reacts with oxygen to form nitrogen and water, or nitrogen (II) oxide and water.
    • Saad Shaik
       
      Properties of Ammonia
  • High pressure conditions (150-250 bar) are used, and temperatures range from 752-932°F (400-500°C).
    • Saad Shaik
       
      Shifts Equilibrium so more Ammonia is made
    • Amy Chern
       
      Reactants are reused to make proccess more efficient
  • ...34 more annotations...
  • boiling point -28.03°F [-33.35°C]
    • Shirley Lu
       
      gas at room temperature
  • high-pressure catalytic reactions of nitrogen (from air) with hydrogen
    • Yeva Berkovich
       
      high pressure because it pushes the forward reaction
    • Amy Chern
       
      shift equilibrium as far to the right as possible to increase yield and to speed up production rate- high pressure and catalyst
  • The largest use of ammonia is in fertilizers,
    • Saad Shaik
       
      this is why ammonia is so important
  • may have been the source of nitrogen for the earliest forms of life, although much controversy exists over the details
    • Nina Chen
       
      It is still debated whether or not the early life forms used nitrogen. Not enough evidence may be known.
  • German chemists Fritz Haber and Carl Bosch learned how to make ammonia in large quantities by high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
    • Amy Chern
       
      Shift equilibrium as far to the right as possible to increase yield and to speed up production - high pressure and catalyst
  • In ancient Egypt, ammonium compounds were used in rites honoring the god Ammon, from which came the name we still use for the gas and its compounds.
    • Joshua Yohannan
       
      this is important because a lot of things originated in ancient egypt
  • Ammonia, composed of three parts hydrogen and one part nitrogen, is a sharp-smelling, flammable, and toxic gas that is very soluble in water, where it acts as a base in its chemical reactions.
    • Saad Shaik
       
      Basic definition and properties of Ammonia
    • Joshua Yohannan
       
      this is basically what ammonia is.
  • In this attraction, called association,
    • Yeva Berkovich
       
      is it always called attraction, or is that just for this molecule?
  • ammonia was sometimes manufactured by the action of steam on calcium cyanamide, called the cyanamide process,
    • Vickie Xin
       
      Previous process of making ammonia - cyanamide process
  • German chemists Fritz Haber and Carl Bosch
    • Joshua Yohannan
       
      eventually they competed against each other because they both wanted to know about ammonia
  • such as Jupiter, where it may have originally formed from metal nitrides reacting with water.
    • james huang
       
      How do we know where liquid and solid ammonia have have formed? Do we know that these theories are correct?
  • The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated.
  • ammonia is able to react with acidic gases such as nitrogen oxides and sulfur oxides to form ammonium salts
    • james huang
       
      Ammonia's special chemical properties allow it to react with acidic gases to form salts.
  • Ammonia is formed from nitrogen in air by the action of nitrogen-fixing bacteria that exist in the soil on the roots of certain plants like alfalfa.
    • Joshua Yohannan
       
      is this the haber process?
  • The synthesis reaction itself produces some heat, and great attention is given to heat efficiency and use of waste heat.
    • Saad Shaik
       
      Being as efficient as possible
    • Shirley Lu
       
      exothermic reaction -- but the rate of the reaction must also be taken into account --> balance between increasing yield (application of Le Chatelier's) and producing the ammonia at an efficient rate
  • which amounts to about 40 pounds (18 kg) for each person on Earth.
    • Joshua Yohannan
       
      it's surprising how much of an impact the haber process made in the world
  • Ammonium hydroxide exhibits the characteristics of a weak base,
    • Vickie Xin
       
      water solution of ammonia is a weak base
  • Much nitrogen is normally excreted by humans (and other mammals) as urea, a water soluble solid, but fish can excrete ammonia directly.
    • Yeva Berkovich
       
      fish are cool
  • These bacteria and algae possess an enzyme called nitrogenase that permits them to convert nitrogen to ammonia at 77°F (25°C) and 1 bar of pressure, much milder conditions than those of the Haber-Bosch process.
    • Saad Shaik
       
      Process can happen naturally
  • Although Earth's atmosphere is free of ammonia
    • Joshua Yohannan
       
      this is surprising because there is ammonia in other atmospheres of other planets
  • feed supplement for cattle, aiding in the rapid building of protein by the animals.
    • Yeva Berkovich
       
      is this good for the well being of cows?
  • presence of an iron catalyst
    • Nina Chen
       
      Speeds up the reaction but doesn't change the equilibrium point
  • nited
  • United States production of ammonia reached 17 million tons in 1991, and demand was even larger than U.S. production, leading to about two million tons of imports.
    • Amy Chern
       
      Haber Process is important because ammonia is in high demand - need to have the most efficient and economical process for producing ammonia
  • the lightest touch will cause it to explode with a crackling sound and a puff of purple iodine vapor.
    • Joshua Yohannan
       
      so creating ammonia through the haber process can be dangerous if not handled with extreme care. should we create as much ammonia as we do?
  • corrosive and volatile ingredient in fuels.
    • Vickie Xin
       
      Ammonia is commonly used in fuels and explosives
  • When dry, this substance is so sensitive that the lightest touch will cause it to explode with a crackling sound and a puff of purple iodine vapor.
    • vinaireddy123
       
      Interesting...
  • strong color
    • Nina Chen
       
      What makes a color 'strong'?
  • New uses may develop, particularly for ammonia as a relatively inexpensive base with unique properties, for liquid ammonia as a solvent, and as a storage medium for hydrogen, as the nations evolve toward alternative fuels.
    • Amy Chern
       
      New uses of Ammonia are continously being discovered
  • For this reason, capacity and production will continue to grow
    • Joshua Yohannan
       
      creation of ammonia will always be important because it helps so much with agriculture and other things.
  • Ammonia can be formed in the human body and may build up abnormally during serious illnesses such as Reye's syndrome.
    • vinaireddy123
       
      What causes this build up of ammonia?
  • New uses may develop, particularly for ammonia as a relatively inexpensive base with unique properties, for liquid ammonia as a solvent, and as a storage medium for hydrogen, as the nations evolve toward alternative fuels.
    • Saad Shaik
       
      unless they find something better
  • 200,000 tons of ammonia were released into the environment
    • Shirley Lu
       
      negative environmental impact
  • earned to generate ammonia from animal parts such as deerhorn, and obtained ammonial preparations
    • Amy Chern
       
      Ammonia has long been used for various purposes.
Miral Tripathi

Gale Science In Context - Document - 14 views

  • Ammonia
    • Mrs. Byrge
       
      NH3
  • Ammonia is manufactured by the reaction of hydrogen with nitrogen in the presence of an iron catalyst, which is known as the Haber-Bosch process.
    • phillip an
       
      Production of ammonia
  • Ammonia (boiling point -28.03°F [-33.35°C])
    • Vaibhav Tiwari
       
      This would mean that Ammonia is a gas at room temperature.
  • ...34 more annotations...
  • In ancient Egypt, ammonium compounds were used in rites honoring the god Ammon, from which came the name we still use for the gas and its compounds.
    • Alicia Stephen
       
      Interesting origins of Ammonia and its name...
  • ammonia was sometimes manufactured by the action of steam on calcium cyanamide, called the cyanamide process, which in turn was made by reacting calcium carbide with nitrogen at high temperatures.
    • vivek shankar
       
      What is the chemical reaction for the cyanamide process?
    • phillip an
       
      CaC2 + N2 → CaCN2 + C
    • phillip an
       
      Further produced calcium cyanamide gives together with water steam calcium carbonate and ammonia: CaCN2 + 3 H2O → CaCO3 + 2 NH3
  • Joseph Priestley (1733-1804) first collected and experimented with the pure substance. C. L. Berthollet (1748-1822) proved that ammonia is composed of nitrogen and hydrogen.
    • Alicia Stephen
       
      Very important that this discovery was made-- otherwise there would be no deerhorn left..
  • The largest use of ammonia is in fertilizers, which are applied to the soil and help provide increased yields of crops such as corn, wheat, and soybeans. Liquid ammonia, ammonia/water solutions, and chemicals made from ammonia, such as ammonium salts and urea, are all used as sources of soluble nitrogen. Urea, which is made from ammonia and carbon dioxide, can also be used as a feed supplement for cattle, aiding in the rapid building of protein by the animals.
    • phillip an
       
      Ammonia is used in many facets of daily life
  • by high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
    • Alexa Wisniarek
       
      Using pressure to shift the equilibrium.
    • Miral Tripathi
       
      Talks about pressure but not about tempurature.
  • The copper (II) ammonia complex, in solution, is deep blue in color,
    • Vaibhav Tiwari
       
      We learned this in periodicty, the colors of the transition metals, and copper is blue.
  • German chemists Fritz Haber and Carl Bosch learned how to make ammonia in large quantities by high-pressure catalytic reactions of nitrogen (from air) with hydrogen.
  • The Haber-Bosch process is the basis for modern ammonia production, although many improvements have been made in the details of the technology.
    • Alicia Stephen
       
      How ammonia is produced
  • be made in the laboratory by heating ammonium chloride with lime, and the gas collected by downward displacement of air, or displacement of mercury.
    • Miral Tripathi
       
      The actual process of making ammonia
  • a weak base, turning litmus paper blue, and neutralizing acids with the formation of ammonium salts.
    • Alicia Stephen
       
      Characteristics of Ammonia..
    • vivek shankar
       
      Litmus test gives an indication of how acidic a substance is; the color the Litmus paper turns is related to a specific pH value
  • Ammonium nitrate is used as a high explosive; ammonium perchlorate is a component of rocket fuels.
    • Alexa Wisniarek
       
      It's used for both "good purposes", like fertilizer, and "bad" purposes, like weapons.
  • ability to dissolve cellulose, and has been used in the process for making regenerated cellulose fibers, or rayon.
    • Alicia Stephen
       
      This is really interesting... guess that explains why we can't digest cellulose...
  • Ammonia molecules possess a pyramidal shape, with the nitrogen atom at the vertex.
  • Ammonia molecules possess a pyramidal shape, with the nitrogen atom at the vertex.
    • Alicia Stephen
       
      Shapes of molecules.. we learned this sophomore chem (VSEPR)
  • (The ammonia occupies less volume than the gases from which it is made.) High pressure conditions (150-250 bar) are used, and temperatures range from 752-932°F (400-500°C). The mixed gases circulate through the catalyst, ammonia is formed and removed, and the unconverted reactants are recirculated.
    • Alexa Wisniarek
       
      High pressure. High temperature, even though there would be more Ammonia production at low temeperature, to speed up the rate of reaction.
  • Nitrogen fixation
    • Vaibhav Tiwari
       
      Will we learn about Nitrogen Fixation in chem, or is it in bio, or neither or them?
    • phillip an
       
      Nitrogen fixation is a process by which nitrogen in the atmosphere is converted into ammonia, so i would think we would learn about it in chem
  • Ammonium salts such as ammonium chloride, called sal ammoniac, are water soluble and volatile when heated.
    • Alicia Stephen
       
      What are the salts used for?
  • The gases that enter the catalytic converter must be highly purified and free of sulfur compounds, which adversely affect the catalyst.
    • Alexa Wisniarek
       
      Interesting that sulfur adversely affects the catalyst.
  • Nitric acid and nitrates are needed for the manufacture of explosives like TNT, nitroglycerin, gunpowder, and also for the propellants in cartridges for rifles and machine guns.
    • Vaibhav Tiwari
       
      If all other important nitrogen chemicals are now made from ammonia, wouldn't that cause a shortage in Ammonia? Earlier in the reading it said that the production of Ammonia did not meet its demands and it had to be imported, if we stopped making it for Nitric acid and other nitrates that are used for explosives, we wouldn't have such a shortage.
  • When ammonium hydroxide is treated with iodine crystals, an explosive brown solid, nitrogen triiodide, is formed.
    • james huang
       
      Example of chemical reaction with the use of ammonia.
  • Two types of polymers needed for artificial fibers require the use of ammonia, polyamides (nylon), and acrylics (orlon).
  • where it may have originally formed from metal nitrides reacting with water.
    • james huang
       
      How do we know the origins of why liquid and solid ammonia exist on other planets? Where is the proof regarding this theory?
  • Since the hydrogen is usually derived from a natural gas called methane, the price of ammonia is very sensitive to the availability or price of fuels.
    • Alicia Stephen
       
      Not the easiest thing to predict.. not much stability
  • These bacteria and algae possess an enzyme called nitrogenase that permits them to convert nitrogen to ammonia at 77°F (25°C) and 1 bar of pressure, much milder conditions than those of the Haber-Bosch process.
    • Alexa Wisniarek
       
      Really interesting and neat that they can do that.
  • Ammonia will continue to be important for agriculture and for the whole nitrogen chemicals industry.
    • james huang
       
      Ammonia and its impact in the future. Ammonia has served many purpose in the past, present and in the years to come.
  • blue-green algae in the sea.
    • Alicia Stephen
       
      So can it form in the sea, or no?
  • Ammonia has also been detected in interstellar space by radioastronomy.
    • phillip an
       
      Is ammonia correlated with the origin of life?
  • ammonia is able to react with acidic gases such as nitrogen oxides and sulfur oxides to form ammonium salts
    • james huang
       
      What basic properties allow Ammonia to react with acidic gases and form salts?
  • planets
  • In liquid or frozen ammonia, the molecules attract one another through sharing a hydrogen atom between one molecule and the next, called hydrogen bonding. In this attraction, called association, compounds apparently containing free electrons can be obtained by treating sodium/ammonia solutions with complexing agents.
    • Miral Tripathi
       
      Properties of bonding
  • Ammonia has also been detected in interstellar space by radioastronomy.
    • Alicia Stephen
       
      Interesting.. can we ever get to a point where we can get ammonia from "interstellar space"?
  • , as the nations evolve toward alternative fuels.
    • Alexa Wisniarek
       
      Will Ammonia change the transportation of the future?
  • Asia and Latin America develop higher standards of living and stronger economies, they will need their own ammonia plants.
    • Alicia Stephen
       
      This is pretty important for powerful countries
  • Ammonia is a flammable gas and reacts with oxygen to form nitrogen and water, or nitrogen (II) oxide and water.
    • Miral Tripathi
       
      Ammonia is combustable
  •  
    B3 Annotation
phillip an

Gale Science In Context - Document - 1 views

  • Ammonia
    • phillip an
       
      NH3
  • Its boiling point is about -27.4°F (-33.3°C) making it easy to liquefy at low temperatures.
    • phillip an
       
      One can use this information to optimize the production of ammonia through the Born-Haber process
  • Ammonia is also used to produce salts such as ammonium nitrate and ammonium phosphate for use as commercial fertilizers. It is used in the manufacture of nylon and rayon and for scouring cotton, wool, and silk.
    • phillip an
       
      Not only is ammonia solely used for commercial and manufactoring uses, but also can be utilized militarily. It can be used to make weapons and other instruments of war. However, is the cost of producing future weapons of mass destruction worth the civilian uses of ammonia?
    • Saad Shaik
       
      oh interesting thought. indeed, ammonia would be better used for growing food instead of making weapons
  • ...6 more annotations...
  • plants are not able to assimilate gaseous nitrogen unless it is converted to ammonia or some other form.
    • Saad Shaik
       
      nitrogen is useless unless it is converted to ammonia first. then it can be used as a fertilizer. ammonia is very important
  • Biological nitrogen fixation, which forms ammonia from atmospheric nitrogen and hydrogen supplied by the organism, is also an important source of ammonia for plant growth.
    • Saad Shaik
       
      this is slower then the haber-bosch process right?
  • the use of a catalyst, high pressure (100-1,000 atmospheres), and temperatures of 750-1200° F (400-650°C).
    • Saad Shaik
       
      maximize the amount of ammonia produced due to equilibrium shitfing to the right
  • Ammonia is one of the most widely used compounds in the United States, serving as a raw material for the production of many important compounds and as a nutrient for the growth of crops.
    • Saad Shaik
       
      ammonia is very important because of their fertilizing properties
  • Both free-living and symbiotic bacteria are known to carry out this reductive fixation process.
    • phillip an
       
      Can you use the bacteria to produce ammonia in mass amounts?
  • An especially important example involves Rhizobium bacteria in root nodules of leguminous plants, and is the basis for the common agricultural practice of growing legumes in rotation with other crops to enrich fields with available nitrogen.
    • phillip an
       
      This is an effective way to enchance crop yeild while saving money by doing the natural way
Kaeley McGrane

Gale Science In Context - Document - 0 views

  • 2004
    • Kaeley McGrane
       
      What, if anything, has developed with this discovery since the publication of this article?
Ngo Thien Quy

Gale Science In Context - Document - 1 views

  • A NEWLY invented metal compound can loosen the chemical bonds of the nitrogen molecules that make up four-fifths of the atmosphere
    • Ngo Thien Quy
       
      In our atmosphere, the reactions between nitrogen and oxygen are in dynamic equilibrium where they continue to react. Surprisingly, nitrogen seems to be more abundant than oxygen is.
  • it must first be converted into ammonia (N[H.sub.3]), using an industrial process called Haber-Bosch, in which an iron catalyst is used to crack open the triple bond of the nitrogen molecule, at high temperature and pressure
    • Ngo Thien Quy
       
      Nitrogen is basically unnecessary when it hasn't been broken down or reacted, becuase the nutrients from nitrogen are not able to be used.
Rajmund Niwinski

Gale Science In Context - Document - 2 views

  • iron-catalyzed Haber-Bosch process for ammonia synthesis
    • Rajmund Niwinski
       
      The Haber process involves using overflow of reactants and removal of products to maximize ammonia production.
  • 150 to 550 atmospheres
    • Rajmund Niwinski
       
      We learned that it was 200 atm. Which is it really?
  • high temperatures
    • Rajmund Niwinski
       
      These are needed to keep a high forward reaction rate.
  • ...11 more annotations...
  • The metalloenzymes, called nitrogenases
    • Rajmund Niwinski
       
      These act like the iron catalyst in the Haber process.
  • more energy-efficient process than Haber-Bosch
    • Rajmund Niwinski
       
      Interesting: The same process has been used for almost a hundred years.
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones.
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones.
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones.
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
  • Perhaps a thousand man-years and billions of dollars have been spent studying how nitrogenases work and trying to make artificial ones
OB Rahim

Gale Science In Context - Document - 1 views

  • Carbon dioxide is the fourth most abundant gas in the atmosphere (after nitrogen, oxygen, and argon)
    • OB Rahim
       
      What about Hydrogen?
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