Group items tagged

The JCO plant needed to mix some high-purity enriched uranium oxide with nitric acid to form uranyl nitrate for shipping. The dissolving and mixing began on September 28, 1999. On the morning of September 30, 1999, three technicians, Hisashi Ouchi, Masato Shinohara, and Yutaka Yokokawa, were running fuel through the last steps of the conversion process. To speed up the process, they mixed the oxide and nitric acid in 10-liter stainless steel buckets rather than in the dissolving tank. In doing so, they followed the practice that JCO had written into its operating manual but which had not received STA approval. For convenience, they added the bucket contents directly to the 45-cm-diameter, water-jacketed precipitation tank rather than to the buffer tank. That was a crucial error because the tall, narrow geometry of the buffer tank was designed to preclude the onset of criticality. In filling the precipitation tank, the crew added seven buckets, amounting to a total of about 16 kg (35 lbs of enriched uranium, or roughly seven times more uranium than permitted under the STA license. The three technicians were working in a small processing bay. Masato Shinohara stood on a platform and was pouring the uranyl nitrate solution into the precipitation tank while Hisashi Ouchi held a glass funnel in an inlet at the top of the tank. The third technician, Yutaka Yokokawa, was seated at a desk approximately 4 meters (13 feet) away from the precipitation tank. At approximately 10:35 a.m. the technicians added the seventh bucket and saw a blue flash. The two technicians near the vessel began to experience pain, waves of nausea, some difficulty in breathing, and problems with mobility and coherence. The gamma radiation alarms activated immediately. The blue flash that they had seen was a result of the Cherenkov radiation that is emitted when nuclear fission takes place and ionizes air. The addition of the seventh bucket had caused a self-sustaining chain reaction. The mixture, in other words, had gone critical. Mixing in the precipitation tank caused the fissile uranium species to disperse so that the reaction fizzled out. However, the critical mass later reassembled, initiating another chain reaction that released more neutrons and gamma radiation. This cycle was repeated several times over many hours.

New Nuclear Power Technologies Introduction: There are many new waste disposal technologies which could prove to be somewhat of a solution to the problem of nuclear waste. Reprocessing, The Missing Step: Although not a new technology, reprocessing can be part of the solution to nuclear waste. When nuclear power was first developed, it was assumed that spent nuclear fuel would go through a process called reprocessing. In reprocessing, one of the major transuranic wastes, 239Pu, is extracted from the spent fuel rods. This 239Pu (plutonium-239) is fissile and can be reused in power plants. The advantages of this process are somewhat obvious: The volume of waste is lessened and more fuel is created for nuclear reactors. However, as with all things, politics can get in the way. In the US plutonium reprocessing was banned because the recovered 239Pu is weapons grade material. If, after reprocessing, the fuel is stolen, it could be used by anyone to construct a nuclear weapon. As of a few years ago, the ban against reprocessing in the US was lifted, but there are still no operating reprocessing plants in the US because of the heavy regulations and the anti-nuclear sentiment of the general public. There are a few countries which do reprocessing, however. France, for instance, regularly reprocesses its spent fuel. High Temperature Breeder Reactors: Many of us are familiar from television (and hopefully not from real life experience) of the bar-room game in which a very large man holds a mug of beer on top of his head and challenges people to punch him. If his opponent punches him hard enough, the beer falls off and spills all over the man holding it. The harder the punch, the better chance that the beer will fall off and the puncher will win. Also, the bigger the man is who is getting punched, the harder the punch must be to knock the beer down. You might be wondering why we are talking about a bar-room game. Think of the guy holding the beer as an atom and the guy punching as a neutron. The transuranic elements are bigger than uranium and generally don't fission (get their beer knocked off) in a regular reactor. The neutrons aren't excited enough (don't punch hard enough) to induce fission in them. However, if they are placed in a high-temperature reactor in which the neutrons are much more excited (and carry more punch), there is a much better chance that they will fission. In a reactor being developed by Argonne National Laboratory in the US, almost 100% of the transuranic nuclear wastes produced through neutron capture can be caused to fission. Generally, the fission products created have shorter half-lives and are not as dangerous. This reactor, dubbed EBR-II, uses liquid sodium as a coolant, which means that the internal reactor temperature is much, much hotter than that of a normal PWR reactor, which uses water as a coolant. Another advantage of EBR-II is that its fuel is not weapons grade quality. When the transuranic wastes are separated from the other wastes in the spent fuel rods, the resultant mix of isotopes can not be used in a bomb. Thus, the mix can be used as fuel for EBR-II without a chance of it getting stolen by a terrorist group for use in an explosive device. Breeder reactors "breed" fuel. That is, they are designed to create 239Pu from 238U through neutron capture. This "waste" can then be used as fuel.