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Snaplr is a simple way to capture and annotate your desktop's activity. Its Free to download. After taking your screenshot, you can highlight a specific screenshot area further with a set of drawing tools. Copy your screenshot to the clipboard and paste it to an email or save it as a png attachment instead.  Works great in Gmail and Outlook. I like using this in Windows as Google Chrome doesn't have the best screen capture extensions right now that can annotate as easily as this tool.